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Metallurgical Transactions

, Volume 2, Issue 9, pp 2655–2663 | Cite as

Solubility of hydrogen in solid Ni−Co and Ni−Cu alloys

  • F. G. Jones
  • R. D. Pehlke
Physical Chemistry

Abstract

The solubility of hydrogen was measured in solid Ni, Co, and Cu, and in the Ni−Co and Ni−Cu systems. A unique sampling technique was used in which equilibrated specimens were quenched by dropping into mercury. The measurements were made as a function of temperature in the range from 700° to 1225°C and of hydrogen pressure, up to 1 atm. Dissolved hydrogen in all metals and alloys obeyed Sieverts' Law. An attempt was made to correlate the hydrogen solubility with solution models based on the electronic structure of the alloys. A nonlinear correlation was found with the electronic specific heat coefficient which relates to the density of states at the Fermi surface.

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Copyright information

© The Metallurgical Society of American Institute of Mining, Metallurgical, and Petroleum Engineers, Inc., and American Society for Metals 1971

Authors and Affiliations

  • F. G. Jones
    • 1
  • R. D. Pehlke
    • 2
  1. 1.General Electric CompanyEdmore
  2. 2.The University of MichiganAnn Arbor

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