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Efficiency of certain chromate-free pigments for the corrosion protection of galvanized steel

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Abstract

By using electrochemical methods of a.c. and d.c. and electron microscopy, we investigated the corrosion behavior of galvanized steel in a slightly acid medium that simulates atmospheric precipitation and contains extracts of chromate and chromate-free pigments. We established that the joint use of phosphate and calcium-containing pigments can ensure efficient corrosion protection on a par with chromate pigments due to the formation of a phosphate film with high barrier properties on a metal.

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References

  1. E. C. Porter, “Painting of zinc surfaces,”British Corrosion J.,4, 179–186 ( 1969).

    CAS  Google Scholar 

  2. U. R. Evans,Corrosion and Oxidation of Metals. Arnold. London (1960).

    Google Scholar 

  3. H. H. Uhlig, D. N. Triadis. and M. Stern, “Effect of oxygen, chlorides, and calcium ion corrosion inhibition of iron by polyphosphates. ”J. Electruchem. Soc.,102. 59–65 (1955).

    Article  CAS  Google Scholar 

  4. Z. Szklarska-Smialowska and J. Mankowski, “Le mecanisme de l’action des polyphosphates comme inhibiteurs de la corrosion de l’acier par l’eau,”Centre Belge D’etude Et De Documentation Des Eaux,20. No. 288, 474–480 (1967).

    CAS  Google Scholar 

  5. B. A. Boukamp.Equivalent circuit. Version 3.97. Faculty of Chemical Technology, Twente University (1989).

  6. Acid Rain.A Review of the Phenomenon in EEC and Europe. A Report Prepared for the Commission of the European Communities. Directorate General for Environment, Consumer Protection and Nuclear Safety Environmental Resources Lim. Graham and Trofman Lim. Brussels (1983).

  7. Z. Kemer and T. Pajkossy. “Impedance of rough capacitive electrodes: the role of surface disorder,”J. Electroanalytical Chem.,448. 139–142(1998).

    Article  Google Scholar 

  8. U. Rammelt and G. Reinhard. “On the applicability of a constant phase element (CPE) to the estimation of roughness of solid metal electrodes,”Electmchimica Acta.35. 1045–1049 (1990).

    Article  CAS  Google Scholar 

  9. G. N. Bhar, N. C. Debnath. and S. Roy. “Effects of calcium ions on the morphology and corrosion resistance of zinc-phosphated steel.”Surf. Coat. Tech.,35. 171–179 (1988).

    Article  CAS  Google Scholar 

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 36, No. 3, pp. 112–114. May-June. 2000.

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Zin, I.M. Efficiency of certain chromate-free pigments for the corrosion protection of galvanized steel. Mater Sci 36, 450–453 (2000). https://doi.org/10.1007/BF02769610

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