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Analysis of the effect of temperature on complex self-oscillation regimes in the belousov-zhabotinskii reaction in a constant-agitation flow-through reactor

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Abstract

Modeling of the influence of temperature on complex self-oscillation regimes in the BZ reaction in a CAFT has been carried out. It is shown that the onset of relaxation oscillations as the temperature is raised results from bifurcation of the onset of an infinite period. The disappearance of the oscillations as the temperature is raised further is due to a Hopf bifurcation. The results of the modeling are in qualitative agreement with the experimental data.

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References

  1. G. P. Misra, Chem. Phys. Lett.,191, No. 5, 435–440 (1992).

    Article  CAS  Google Scholar 

  2. P. E. Strizhak and O. Z. Didenko, Teor. Éksp. Khim.,31, No. 2, 69–75 (1995).

    CAS  Google Scholar 

  3. L. Gyorgyi and R. J. Field, J. Phys. Chem.,95, No. 17, 6594–6602 (1991).

    Article  CAS  Google Scholar 

  4. W. Prior, Free Radicals [Russian translation], Atomizdat, Moscow (1970).

    Google Scholar 

  5. G. W. Gear, Math. Comp.,21, 146 (1967).

    Article  Google Scholar 

  6. F. Argoul, A. Arneodo, P. Richetti, and J. C. Roux, J. Chem. Phys.,86, 3325 (1987).

    Article  CAS  Google Scholar 

  7. G. Kshirsagar and R. J. Field, J. Phys. Chem.,92 No. 25, 7074–7079 (1988).

    Article  CAS  Google Scholar 

  8. H.-D. Forsterling, S. Muranyi, and H. Schreiber, Z. Naturforsch. A.,44, No. 6, 555–566 (1989).

    Google Scholar 

  9. P. Forester, S. C. Muller, and B. Hess, J. Phys. Chem.,94, No. 26, 8859–8861 (1990).

    Article  Google Scholar 

  10. M. F. Crowley and R. J. Field, J. Phys. Chem.,88, No. 4, 762–766 (1984).

    Article  CAS  Google Scholar 

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L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 252039 Kiev, Prosp. Nauki, 32. Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 33, No. 3, pp. 159–164, May–June, 1997.

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Strizhak, P.E., Didenko, O.Z. Analysis of the effect of temperature on complex self-oscillation regimes in the belousov-zhabotinskii reaction in a constant-agitation flow-through reactor. Theor Exp Chem 33, 133–137 (1997). https://doi.org/10.1007/BF02765910

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  • DOI: https://doi.org/10.1007/BF02765910

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