Journal of Analytical Chemistry

, Volume 55, Issue 2, pp 155–159 | Cite as

Gas-chromatographic determination of monoethanolamine and its salts of inorganic and organophosphorus acids present in combination

  • I. N. Stan’kov
  • V. A. Yarova
  • A. A. Sergeeva
  • I. V. Potashova
  • S. N. Tarasov
  • N. N. Samofalova
Articles
Received:
  • 55 Downloads

Abstract

A gas-chromatographic procedure was proposed for the separate determination of monoethanolamine and its salts of hydrofluoric, hydrochloric, and alkylphosphonic acids in the reaction mixtures formed in the course of detoxication of chemical warfare agents of various classes. The procedure is based on the conversion of monoethanolamine and its salts into acyl derivatives and their elution from a Chromatographie system at different injector temperatures. The determination error is no worse than 5 rel %.

Keywords

Acetic Anhydride Injector Temperature Soman Butyl Acetate Monoethanolamine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    High Resolution Gas Chromatography, Hyver, K.J., Ed., Hewlett-Packard, 1989. Translated under the titleVysokoeffektivnaya gazovaya khromatografiya, Moscow: Mir, 1993, p. 73.Google Scholar
  2. 2.
    Anderson, A.A.,Zhidkostnaya khromatografiya aminosoedinenii (Liquid Chromatography of Amino Compounds), Riga: Zinatne, 1984, p. 118.Google Scholar
  3. 3.
    Stan’kov, I.N., Sergeeva, A.A., and Tarasov, S.N.,Zh. Anal. Khim., 1999, vol. 54.Google Scholar
  4. 4.
    Stan’kov, I.N. and Mikhalkin, A.P.,Zh. Anal. Khim., 1996, vol. 51, no. 6, p. 676.Google Scholar
  5. 5.
    Berezkin, V.G.,Khimicheskie metody v gasovoi khromatografii (Chemical Methods in Gas Chromatography), Moscow: Khimiya, 1980.Google Scholar
  6. 6.
    Reznikov, S.A., Ivashchenko, V.E., and Plaksin, G.E.,Zavod. Lab, 1967, vol. 33, no. 2, p. 258.Google Scholar
  7. 7.
    Grienwood, N.D. and Nursten, H.E.,J. Chromatogr., 1974, vol. 92, no. 2, p. 323.CrossRefGoogle Scholar
  8. 8.
    Soniassy, R., Sandra, P., and Schlett, C,Water Analysis: Organic Micropollutants, Hewlett Packard, 1994. Translated under the titleAnaliz vody: organicheskie mikroprimesi, St. Petersburg: Teza, 1995, p. 161.Google Scholar
  9. 9.
    Stan’kov, I.N., Beresnev, A.N., and Lanin, S.N.,Zh. Anal. Khim., 1991, vol. 46, no. 5, p. 943.Google Scholar
  10. 10.
    Chichibabin, A.E.,Osnovnve nachala organicheskoi khimii (Fundamentals of Organic Chemistry), Moscow: Khimicheskaya literatura, 1963, vol. 1, p. 282.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • I. N. Stan’kov
    • 1
  • V. A. Yarova
    • 1
  • A. A. Sergeeva
    • 1
  • I. V. Potashova
    • 1
  • S. N. Tarasov
    • 1
  • N. N. Samofalova
    • 1
  1. 1.Russian Research Institute of Organic Chemistry and TechnologyMoscowRussia

Personalised recommendations