Synthesis and characterization of cadmium doped lead-borate glasses
Ceramics and Glasses
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Abstract
Cadmium doped lead-borate glasses were prepared from the melts in appropriate proportions of PbO2, H3BO3 and (15–40 mol%) CdO mixture in the temperature range 700–950°C. The infrared spectra of the glasses in the range 400–4000 cm-1 show their structures. No boroxol ring formation was observed in the structure of these glasses. Furthermore, doped cadmium atoms were not seen in tetrahedral coordination. But the conversion of three-fold to four-fold coordination of boron atoms in the structure of glasses was observed.
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Cadmium lead borate glassesPreview
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References
- Adams R V and Douglas R W 1959J. Soc. Glass Technol. 43 147Google Scholar
- Alemi A A and Hinatsu Y Unpublished workGoogle Scholar
- Biscoe J and Warren B E 1938J. Am. Ceram. Soc. 21 287CrossRefGoogle Scholar
- Chekhovskii V G 1985Ffisika I Khimiya Stekla 11 24 (English Translation)Google Scholar
- Doweidar H, Abouzeid M A and El-Damrawi G M 1991J. Phys. D: Appl. Phys. 24 2222CrossRefGoogle Scholar
- Galeener F L, Lucovsky G and Mikkelsen J C 1980Phys. Rev. B22 3983Google Scholar
- Ghoneun N A, El Batul H A, Abdel Shafi N and Azooz M H 1996Proceeding of Egyptian conference of chemistry (Egypt) p. 162Google Scholar
- Griscon D L 1978Borate glasses: Materials science research (New York: Plenum) Ch. 12, p.36Google Scholar
- Hassan A K, Torell L M, Borjesson L and Doweidar H 1992Phys. Rev. B45 12797Google Scholar
- Heaton H M and Moore H 1987J. Phys. Chem. Glasses 28 203Google Scholar
- Hinatsu Y, Doi Y, Ito K, Wakeshima M and Alemi A A 2003J. Solid State Chem. 172 438CrossRefGoogle Scholar
- Ito Y and Miyauchi K 1983J. Non-Cryst. Solids 57 389CrossRefGoogle Scholar
- Kamitsos E I and Karakassides M A 1989J. Phys. Chem. Glasses 30 19Google Scholar
- Kamitsos E I, Karakassides M A and Chryssikos G D 1987Phys. Chem. Glasses 91 1073CrossRefGoogle Scholar
- Kamitsos E I, Patsis A P, Karakassides M A and Chryssikos G D 1990J. Non-Cryst. Solids 126 52CrossRefGoogle Scholar
- Kanehisa M A and Elliot R J 1989Mater. Sci. Engg. B3 163CrossRefGoogle Scholar
- Karthikeyan B and Mohan S 2003Physica B334 298Google Scholar
- Kulkarni A R, Maiti H S and Paul A 1984Bull. Mater. Sci. 6 207Google Scholar
- Martino D Di, Santos L F, Marques A C and Almeida R M 2001J. Non-Cryst. Solids 293 394CrossRefGoogle Scholar
- Moe U K 1965Phys. Chem. Glasses 6 46Google Scholar
- Motke S G, Yawale S P and Yawale S S 2002Bull. Mater. Sci. 25 75Google Scholar
- Robinson J W 1991Practical handbook of spectroscopy (ed.) J W Robinson (USA: CRC Press Inc.) 1st ed., Ch. 5, p. 533Google Scholar
- Scholzelt H 1991Glass: nature, structure and properties (New York: Springer Verlag)Google Scholar
- Yawale S P, Pakade S V and Adgaonkar C S 1995Indian J. Pure & Appl. Phys. 33 35Google Scholar
- Yawale S S, Yawale S P and Adgaonkar C S 2000Indian J. Eng. Mater. Sci. 7 150Google Scholar
- Yiannopoulos Y D, Chryssikos G D and Kamitsos E I 2001Phys. Chem. Glasses 42 164Google Scholar
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