Journal of Chemical Sciences

, Volume 116, Issue 4, pp 215–219 | Cite as

Copper(II), cobalt(II), nickel(II) and zinc(II) complexes of Schiff base derived from benzil-2,4-dinitrophenylhydrazone with aniline



New Schiff base chelates of Cu(II), Co(II), Ni(II) and Zn(II) derived from benzil-2,4-dinitro-phenylhydrazone with aniline have been synthesised. Microanalytical data, molar conductance, and magnetic susceptibility values have been obtained, and IR,1H NMR,13C NMR, UV-Vis, CV and EPR spectral studies have been carried out to suggest tentative structures for the complexes


Benzil-2,4-dinitrophenylhydrazone Schiff base complexes EPR cyclic voltammetry 


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  1. 1.
    Orget L E and Dunit J D 1957Nature (London) 179 462CrossRefGoogle Scholar
  2. 2.
    Ito K and Ito J 1958Aust. J. Chem. 2 406CrossRefGoogle Scholar
  3. 3.
    Goodgame D M L and Cotton F A 1961J. Am. Chem.Soc. 83 4161CrossRefGoogle Scholar
  4. 4.
    Singh A K and Sharma U N 2002Asian J. Chem. 14 1221Google Scholar
  5. 5.
    Sacconi L and Ciampolini M 1964J. Chem. Soc. 276Google Scholar
  6. 6.
    Idcher A D 1963J. Phys. Chem. 67 1214Google Scholar
  7. 7.
    Raman N, Selvan A and Shunmugasundaram A 1997Asian J. Chem. 9 183Google Scholar
  8. 8.
    Raman N, Kulandaisamy A, Thangaraja C and Jeyasubramanian K 2003Transition Met. Chem. 28 29CrossRefGoogle Scholar
  9. 9.
    Raman N, Ravichandran S and Kulandaisamy A 2002Asian J. Chem. 14 1261Google Scholar
  10. 10.
    Geary W J 1971Coord. Chem. Rev. 7 81CrossRefGoogle Scholar
  11. 11.
    Silverstein R M, Bassler G C and Movril T C 1981Spectroscopic identification of organic compounds 4th edn (New York: Wiley)Google Scholar
  12. 12.
    Dunn T M 1960The visible and ultraviolet spectra of complex compounds in modern coordination chemistry (New York: Interscience)Google Scholar
  13. 13.
    Krishna C H, Mahapatra C M and Dush K C 1977J. Inorg. Nucl. Chem. 39 1253CrossRefGoogle Scholar
  14. 14.
    Kasim A N M, Venkappayya D and Prabhu G V 1999J. Indian Chem. Soc. 76 67Google Scholar
  15. 15.
    Chohan Z H and Parvez H H 1993Synth. React. Inorg. Met.-Org. Chem. 23 1061CrossRefGoogle Scholar
  16. 16.
    Sekerci M and Tas E 2000Heteroatom Chem. 11 254CrossRefGoogle Scholar
  17. 17.
    Figgis B N and Lewis J 1960Modern coordination chemistry (New York: Wiley Interscience)Google Scholar
  18. 18.
    Sabastiyan A and Venkappayya D 1990J. Indian Chem. Soc. 67 584Google Scholar
  19. 19.
    Konig E 1971Structure and bonding (Berlin: Springer Verlag) p. 175Google Scholar
  20. 20.
    Rana A K and Shah J R 1981Indian J. Chem. A20 142Google Scholar
  21. 21.
    Cotton F A and Wilkinson G 1962Advanced inorganic chemistry (New York: Wiley Interscience)Google Scholar
  22. 22.
    Figgis B N 1976An introduction to ligand fields (New Delhi: Wiley Eastern)Google Scholar
  23. 23.
    Shirin Z and Mukherjee R M 1992Polyhedron 11 2625CrossRefGoogle Scholar
  24. 24.
    Hathway B J and Billing D E 1961Coord. Chem. Rev. 5 143CrossRefGoogle Scholar
  25. 25.
    Kevelson D and Niedman R J 1961Chem. Phys. 35 149CrossRefGoogle Scholar
  26. 26.
    Shirin Z and Mukherjee R M 1992Polyhedron 11 2625CrossRefGoogle Scholar

Copyright information

© Indian Academy of Sciences 2004

Authors and Affiliations

  1. 1.Department of ChemistryVHNSN CollegeVirudhunagarIndia

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