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Journal of Applied Spectroscopy

, Volume 66, Issue 1, pp 55–61 | Cite as

Polarized fluorescence of radicals in photodissociation of disulfides in the gas phase

  • A. P. Blokhin
  • M. F. Gelin
  • I. I. Kalosha
  • S. A. Polubisok
  • V. A. Tolkachev
Article
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Abstract

The polarization of the fluorescence of radicals formed in laser-induced photodissociation of some disulfides in the gas phase is measured. Experimental data obtained in the study are interpreted within the free recoil model. It is shown that polarization experiments carried out to investigate photodecay in vapors allow researchers to uniquely the intramolecular direction of the dipole moments of transitions with absorption and emission.

Key words

photodissociation radicals disulfides polarized fluorescence 

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References

  1. 1.
    G. A. Chamberlian and J. P. Simons, Chem. Phys. Lett.,32, 355 (1975).CrossRefADSGoogle Scholar
  2. 2.
    G. A. Chamberlian and J. P. Simons, J. Chem. Soc., Faraday Trans.,2, 71, 2043 (1975).Google Scholar
  3. 3.
    G. W. Loge and R. N. Zare, Mol. Phys.,43, 1419 (1981).CrossRefGoogle Scholar
  4. 4.
    G. W. Loge and I. R. Wiesenfeld, J. Chem. Phys.,75, 2795 (1981).CrossRefADSGoogle Scholar
  5. 5.
    T. Nagata, T. Kondow, K. Kuchitsu, G. W. Loge, and R. N. Zare, Mol. Phys.,50, 49 (1983).CrossRefGoogle Scholar
  6. 6.
    P. L. Houston, J. Phys. Chem.,91, 5388 (1987).CrossRefGoogle Scholar
  7. 7.
    T. Nagata, T. Kondow, and R. N. Zare, Mol. Phys.,70, 1159 (1990).CrossRefGoogle Scholar
  8. 8.
    V. A. Povedailo, A. P. Blokhin, M. F. Gelin, and V. A. Tolkachev, Opt. Spektrosk.,73, No. 3, 547 (1992).Google Scholar
  9. 9.
    A. P. Blokhin and M. F. Gelin, Opt. Spektrosk.,74, No. 2, 279 (1993).Google Scholar
  10. 10.
    A. P. Blokhin and M. F. Gelin, Zh. Prikl. Spektrosk.,65, No. 6, 908–914 (1998).Google Scholar
  11. 11.
    A. P. Blokhin, S. P. Pliska, and V. A. Tolkachov, Spectr. Lett.,18, No. 4, 301 (1985)CrossRefGoogle Scholar
  12. 12.
    A. P. Blokhin and M. F. Gelin, Opt. Spektrosk.,77, No. 1, 41 (1994).Google Scholar
  13. 13.
    A. P. Blokhin and M. F. Gelin, Opt. Spektrosk.,77, No. 2, 222 (1994).Google Scholar
  14. 14.
    G. W. Meier, Private Commun.Google Scholar
  15. 15.
    A. P. Blokhin, M. F. Gelin, S. A. Polubisok, V. A. Tolkachev, and A. A. Blokhin, J. Molec. Struct.,408/409, 569 (1997).CrossRefGoogle Scholar
  16. 16.
    T. Bultmann and N. P. Ernstig, J. Phys. Chem.,100, 19417 (1996).CrossRefGoogle Scholar
  17. 17.
    Y. Hirata, Y. Niga, S. Makita, and T. Okada, J. Phys. Chem., A101, 561 (1997).Google Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • A. P. Blokhin
  • M. F. Gelin
  • I. I. Kalosha
  • S. A. Polubisok
  • V. A. Tolkachev

There are no affiliations available

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