Determination of the enthalpy of mixing of liquid alloys using a high-temperature mixing calorimeter

  • U. K. Stolz
  • I. Arpshofen
  • F. Sommer
  • B. Predel
Section II: Basic and Applied Research


A high-temperature mixing calorimeter that allows the measurement of the enthalpy of mixing of liquid alloys at temperatures ranging up to 1800 K is described. The suitability of the apparatus is shown by the measurement of the enthalpy of mixing of liquid Al-Cu, Al-Ni, and Cu-Ni alloys. The results are compared with data from literature and are discussed using an association model.


Enthalpy Liquid Alloy Association Model Equiatomic Composition Filling Height 
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Cited References

  1. 42Gru:.
    G. Grube and P. Hantelmann,Z. Elektrochem.,48, 90 (1942).Google Scholar
  2. 64Ben:.
    M.G. Benz and J.F. Elliott,Trans. Metall Soc. AIME, 230 706 (1964).Google Scholar
  3. 65Dok:.
    R.N. Dokken and J.F. Elliott,Trans. Metall. Soc. AIME 233 1351 (1965).Google Scholar
  4. 65Vac:.
    F. Vachet, P. Desre, and E. Bonnier,Compt. Rend, 260 453 (1965).Google Scholar
  5. 65Wi1:.
    T.C. Wilder,Trans. Metall. Soc. AIME, 233, 1202 (1965).Google Scholar
  6. 66Kha:.
    A. El’Khasan, K. Abdel’-Aziz, A.A. Vertmann, and A.M. Samarin,Izv. Akad. Nauk SSSR,Met.,3, 19 (1966).Google Scholar
  7. 69Mit:.
    H. Mitani and H. Nagai,J. Jpn. Inst. Met.,33, 344 ( 1969).CrossRefGoogle Scholar
  8. 71Dan:.
    H. D. Dannöhl, dissertation, Universität Stuttgart (1971).Google Scholar
  9. 71Pre:.
    B. Predel and R. Mohs,Arch. Eisenhüttenwes.,42(8), 575 (1971).CrossRefGoogle Scholar
  10. 71San1:.
    V.M. Sandakov, Y.O. Esin. and P.V. Geld,Russ. J. Phys Chem 45(7), 1020 (1971).Google Scholar
  11. 71San2:.
    V.M. Sandakov, Y.O. Esin, P.V. Geld, and V.D. Shantarin,Russ. J. Phys. Chem.,45(8), 1150 (1971).Google Scholar
  12. 72Bat:.
    G.I. Batalin, E.A. Beloborodova, and V.N. Vasil’ev,Ukr. Khim. Zh.,38(9), 920 (1972).Google Scholar
  13. 73Hu1:.
    R. Hultgren, R.L. Orr, and K.K. Kelley,Supplement to Selected Values of Properties of Metals and Alloys, American Society for Metals, Metals Park, OH ( 1973).Google Scholar
  14. 74Gau:.
    M. Gaune-Escard and J.P. Bros,Can. Metall. Q.,13, 335 (1974).CrossRefGoogle Scholar
  15. 77Kom:.
    K.L. Komarek,Ber. Bunsenges. Phys. Chem.,81, 936 (1977).CrossRefGoogle Scholar
  16. 78Pre:.
    B. Predel, I. Arpshofen, and M.J. Pool,Thermochim Acta 22 211 (1978).CrossRefGoogle Scholar
  17. 79Arp:.
    I. Arpshofen, B. Predel, E. Schultheiss, and M. Hoch,Thermochim. Acta., 33, 197 (1979).CrossRefGoogle Scholar
  18. 79Poo:.
    M.J. Pool, I. Arpshofen, B. Predel, and E. Schultheiss,Z. Metallkd.,70, 656 (1979).Google Scholar
  19. 79Pre:.
    B. Predel, M.J. Pool, and E. Schultheiss,Thermochim Acta, 28, 343 (1979).Google Scholar
  20. 81Kub:.
    O. Kubaschewski,PhysicaB, 103, 101 (1981).ADSGoogle Scholar
  21. 82Pre:.
    B. Predel,Calphad, 6, 199 (1982).CrossRefGoogle Scholar
  22. 82Som:.
    E Sommer,Z. Metollkd.,73(2), 72,77(1982).Google Scholar
  23. 82Tom:.
    J. Tomiska and A. Neckel,Int. J. Mass. Spec. Ion Phys 47 223 (1982).ADSCrossRefGoogle Scholar
  24. 83Giz:.
    N.V. Gizenko, S.N. Kilesco, D.V. Ilnikov, B.J. Einlin, and A.L. Zavylov,Izv. V. U. Z. Tsvetn. Metall.,4, 21 (1983).Google Scholar
  25. 85Lee:.
    J.J. Lee and F. Sommer,Z. Metallkd.,76, 750 ( 1985).Google Scholar
  26. 87Mey:.
    San Mey.Z. Metallkd.,78(7), 503 (1987).Google Scholar
  27. 88Som:.
    F. Sommer,J. Therm. Anal.,33, 15 (1988).CrossRefGoogle Scholar
  28. 89Hey:.
    E. Heyer, Universität Wien, Austria, private communication (1989).Google Scholar
  29. 89Sri:.
    S. Srikanth and K.T. Jacobs,Metall. Sci. Technol, 5, 427 (1989).CrossRefGoogle Scholar
  30. 90Hi1:.
    K. Hilpert, M. Miller, H. Gerads, and H. Nickel,Ber. Bunsenges Phys. Chem.,94, 40 (1990).CrossRefGoogle Scholar
  31. 90Sud:.
    VS. Sudavtsova, A.V. Shuvalov, and N.O. Sharkina,Rasplavy 4, 97 (1990).Google Scholar
  32. 91Kek:.
    S. Kek, Dissertation, Universität Stuttgart (1991).Google Scholar
  33. 91Sau:.
    N. Saunders, Report to NPL, No. NPL82/B/0544(1991).Google Scholar
  34. 91Sto:.
    U. K. Stolz, Diplomarbeit Universität Stuttgart(1991).Google Scholar

Copyright information

© ASM International 1993

Authors and Affiliations

  • U. K. Stolz
    • 1
    • 2
  • I. Arpshofen
    • 1
    • 2
  • F. Sommer
    • 1
    • 2
  • B. Predel
    • 1
    • 2
  1. 1.Max-Planck-Institutfür Metallforschung Institut für WerkstqffwissenschaftUSA
  2. 2.Institut für Metallkunde der Universität StuttgartStuttgartGermany

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