Journal of Phase Equilibria

, Volume 15, Issue 3, pp 240–263 | Cite as

Systematic aspects of the high-temperature thermochemistry of binary alloys and related compounds

  • O. J. Kleppa
Article
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Abstract

In order to obtain reliable information on the high- temperature thermodynamics of binary alloys and related compounds, the modern investigator has a range of different experimental methods at his disposal: vapor pressure measurements, the emf technique, solubility measurements, and high-temperature reaction calorimetry. It is now more than 40 years since we first analyzed these prob-lems in some detail. We recognized, of course, that reaction calorimetry alone cannot provide a complete picture of the thermodynamics of any system. On the other hand, we also knew that the en-thalpy contributions to the excess Gibbs energies of alloys usually outweigh the corresponding en-tropy terms. We concluded that, among these various experimental methods, high- temperature reaction calorimetry should be the most useful approach in any attempt to gain systematic thermo-dynamic information on alloy systems. We accordingly decided to pursue a program of research cen-tered on alloy high- temperature thermochemistry. A review is presented of the development of the modern high- temperature reaction calorimeter and of the application of calorimetric measurements to a wide range of binary alloy systems and related compounds.

Keywords

Calorimeter Standard Enthalpy Late Transition Metal Reaction Calorimetry Binary Liquid Alloy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© ASM International 1994

Authors and Affiliations

  • O. J. Kleppa
    • 1
  1. 1.The James Franck InstituteThe University of ChicagoChicago

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