Metallurgical Transactions A

, Volume 24, Issue 9, pp 1943–1955 | Cite as

Transmission electron microscopy examination of hardening and toughening phenomena in Aermet 100

  • Raghavan Ayer
  • P. M. Machmeier
Transformations

Abstract

The effect of tempering on the microstructure and mechanical properties of ultrahigh strength Aermet 100 steel was examined. In the as-quenched condition, the steel contained a dispersion of relatively fine, undissolved, (CrTiFeMo)C and (CrFeMo)23C6 carbides in a martensitic matrix. Upon tempering at 427 °C, the martensite decomposed to form a high density of cementite particles concomitant with a significant drop in toughness. Tempering at 454 °C resulted in peak strength (yield strength ∼ 1756 MPa) due to the precipitation of coherent zones of fine carbides. The peak in toughness (170 MPa√m), attained at a tempering temperature of 482 °C, was attributed to both the absence of cementite and the formation of reverted, stable austenite. Tempering at higher temperatures resulted in loss of both strength and toughness, which was suggested to be the result of precipitate coarsening and formation of unstable austenite, respectively. The details of the electron microscopy studies and mechanism of strengthening and toughening are discussed in light of the current understanding of this subject.

Keywords

Austenite Martensite Metallurgical Transaction Cementite Cementite Particle 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    K. H. Jack:J. Iron Steel Inst., 1951, Nov. 1, pp. 26–3611.Google Scholar
  2. 2.
    G. W. Greenwood:Acta Metall., 1956, vol. 4, pp. 243–48.CrossRefGoogle Scholar
  3. 3.
    K. J. Irvine:J. Iron Steel Inst., 1962, Oct. 2, pp. 820–33.Google Scholar
  4. 4.
    D. Raynor, J. S. Whiteman, and R. W. K. Honeycombe:J. Iron Steel Inst., 1966, Nov., pp. 1114–16.Google Scholar
  5. 5.
    D. Raynor, J. A. Whiteman, and R. W. K. Honeycombe:J. Iron Steel Inst., 1966, Apr., pp. 349–54.Google Scholar
  6. 6.
    DJ. Dyson, S. R. Keown, D. Raynor, and J. A. Whiteman:Acta Metall., 1966, vol. 14, pp. 867–75.CrossRefGoogle Scholar
  7. 7.
    T. Mukherjee, W. E. Stumpf, CM. Seilars, and W. J. McG Tegart:J. Iron Steel Inst., 1969, May, pp. 621–31.Google Scholar
  8. 8.
    S. Murphy and J. A. Whiteman:Met. Sci. J., 1970, vol. 4, pp. 58–62.Google Scholar
  9. 9.
    A. T. Davenport and R. W. K. Honeycombe:Met. Sci. J., 1975, vol. 9, pp. 201–08.CrossRefGoogle Scholar
  10. 10.
    D. M. Davies and B. Ralph:J. Iron Steel Inst., 1972, Apr. , pp. 262–66.Google Scholar
  11. 11.
    J. J. Irani and R. W. K. Honeycombe:J. Iron Steel Inst., 1965, Aug. , pp. 826–33.Google Scholar
  12. 12.
    T. Tanino, T. Nishida, and K. Aoki:J. Iron Steel Inst., 1967, Aug. , pp. 874–75.Google Scholar
  13. 13.
    R. A. Clark and G. Thomas:Metall. Trans. A, 1975, vol. 6A, pp. 969–79.Google Scholar
  14. 14.
    V. K. Chandhok, J. P. Hirth, and E. J. Dulis:Trans. ASM, 1963, vol. 56, pp. 677–93.Google Scholar
  15. 15.
    V. K. Chandhok, J. P. Hirth, and E. J. Dulis:Trans. AIME, 1962, vol. 224, pp. 858–64.Google Scholar
  16. 16.
    G. R. Speich, D. S. Dabkowski, and L. F. Porter:Metall. Trans., 1973, vol. 4, pp. 303–15.CrossRefGoogle Scholar
  17. 17.
    G. R. Speich: inInnovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds. , U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 89–111.Google Scholar
  18. 18.
    P. M. Machmeier, C. D. Little, M. H. Horowitz, and R. P. Oates:Met. Technol., 1979, pp. 291–96.Google Scholar
  19. 19.
    CD. Little and P. M. Machmeier: U. S. Patent 4,076,525, 1978.Google Scholar
  20. 20.
    G. B. Olson: inInnovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds., U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 3–66.Google Scholar
  21. 21.
    G. M. Carinci, G. B. Olson, J. A. Liddle, L. Chang, and G. D. W. Smith: inInnovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds. , U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 179–208.Google Scholar
  22. 22.
    J. S. Montgomery and G. B. Olson: inInnovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds. , U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 147–78.Google Scholar
  23. 23.
    G. Haidemenopoulos, G. B. Olson, and M. Cohen:in Innovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds. , U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 549–93.Google Scholar
  24. 24.
    M. Schmidt and M. Gore: inInnovations in Ultrahigh Strength Steel Technology, Proc. 34th Sagamore Army Materials Research Conf., G. B. Olson, M. Azrin, and E. S. Wright, eds. , U. S. Army Materials Technology Laboratory, Watertown, MA, 1990, pp. 407–24.Google Scholar
  25. 25.
    J. A. Liddle, G. D. W. Smith, and G. B. Olson:Proc. 33rd Int. Field Emission Symp., appeared inJ. Phys., 1986, vol. 47, pp. C7-223–C7-31.Google Scholar
  26. 26.
    G. B. Olson, T. J. Kinkus, and J. S. Montgomery:Surf. sci., 1991, vol. 246, pp. 238–45.CrossRefGoogle Scholar
  27. 27.
    G. Haidemenopoulos, M. Grujicic, G. B. Olson, and M. Cohen:Acta Metall., 1989, vol. 37, pp. 207–18.Google Scholar
  28. 28.
    M. J. Gore, G. B. Olson, and M. Cohen:Acta Metall., 1989, vol. 37, pp. 425–41.Google Scholar
  29. 29.
    K. J. Handerhan, W. M. Garrison, Jr. , and N. R. Moody:Metall. Trans. A, 1989, vol. 20A, pp. 105–23.Google Scholar
  30. 30.
    H. M. Lee, A. J. Garratt-Reed, and S. M. Allen:Scripta Metall. Mater., 1991, vol. 25, pp. 685–88.CrossRefGoogle Scholar
  31. 31.
    M. Schmidt and R. Hemphill:Scripta Metall. Mater., 1991, vol. 25, pp. 239–60.CrossRefGoogle Scholar
  32. 32.
    P. M. Novotny: inFundamentals of Aging and Tempering in Bainite and Martensitic Steel Products, Gilbert Speich Symp. Proc, Iron and Steel Society, Warrendale, PA, 1992, pp. 215–36.Google Scholar
  33. 33.
    Raghavan Ayer and P. Machmeier: inMicrostructure and Mechanical Properties of Aging Materials, Int. Symp., ASM, Metals Park, OH, 1992.Google Scholar
  34. 34.
    R. L. Miller:Trans. ASM, 1964, vol. 57, pp. 892–99.Google Scholar
  35. 35.
    B. E. Warren:J. Appl. Phys., 1941, vol. 12, pp. 375–89.CrossRefGoogle Scholar
  36. 36.
    B. E. Warren and B. L. Averbach:J. Appl. Phys., 1950, vol. 21, pp. 21–34.CrossRefGoogle Scholar
  37. 37.
    P. Ganesan, H. K. Kuo, A. Saavedra, and R. J. DeAngelis:J. Catalysis, 1978, vol. 52, pp. 310–20.CrossRefGoogle Scholar
  38. 38.
    G. Thomas:Metall. Trans. A, 1978, vol. 9A, pp. 439–50.Google Scholar
  39. 39.
    H. Smith and D. R. F. West:J. Mater. sci., 1973, vol. 8, pp. 1413–20.CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals and Materials Society, and ASM International 1993

Authors and Affiliations

  • Raghavan Ayer
    • 1
  • P. M. Machmeier
    • 2
  1. 1.STEM, Inc.Woodbridge
  2. 2.Snap-on Tools Corp.Kenosha

Personalised recommendations