The h- sc (Hydrogen- Scandium) system

  • F. D. Manchester
  • J. M. Pitre


Electron Spin Resonance Equi Diagram Scandium Crys Structure Hexagonal Lattice 
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Cited References

  1. 42Lif:.
    E.M. Lifshitz, “On the Theory of Phase Transitions of the Second Order I,”J. Phys. U.S.S.R., 6, 61–74 (1942); II,J. Phys. U.S.S.R., 6, 251-263 (1942). (Crys Structure; Experimental)MathSciNetGoogle Scholar
  2. 48Blo:.
    N. Bloembergen, E.M. Purcell, and R. V. Pound, “Relaxation Effects in Nuclear Magnetic Resonance Absorption,”Phys. Rev., 73, 679–712 (1948). (Crys Structure; Theory)CrossRefADSGoogle Scholar
  3. 60Bec:.
    R.L. Beck, “Research and Development of Metal Hydrides,” USAEC Report LAR-10, Sept (1960), Denver Research Institute, Nov (1960). (Equi Diagram, Thermo; Experimental; #)Google Scholar
  4. 60Mcg:.
    J.C. McGuire andC.P. Kempter, “Preparation and Properties of Scandium Dihydride,”J. Chem. Phys., 33, 1584–1585 (1960). (Equi Diagram, Crys Structure; Experimental)CrossRefADSGoogle Scholar
  5. 65Aza:.
    Z.M. Azarkh and V.N. Funin, “X-Ray Structural Phase Analysis of the Scandium-Hydrogen System,”Kristallografiya, 10, 29–31 (1965) in Russian; TR:Sov. Phys. Crystallogr., 10, 21-23 (1965). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  6. 65Lie:.
    M.L. Lieberman and P.G. Wahlbeck, “The Thermodynamics of the Scandium-Hydrogen System,”J. Phys. Chem., 69, 3514–3519 (1965). (Equi Diagram, Thermo; Experimental; #)CrossRefGoogle Scholar
  7. 66Har:.
    K.I. Hardcastle and J.C. Warf, “Rare Earth-Hydrogen Systems. III. High-Pressure Investigations,”Inorganic Chem., 5, 1728–1735 (1966). (Equi Diagram; Experimental)CrossRefGoogle Scholar
  8. 66Mac:.
    J.R. MacDonald, “Some Simple Equations of State,”Rev. Mod. Phys., 38, 669–679 (1966). (Thermo; Review)CrossRefADSGoogle Scholar
  9. 66Sta:.
    J.F. Stampfer, “The Scandium-Hydrogen System,” Los Alamos Sci. Lab. Report, LA-3473 ”. (Equi Diagram, Thermo; Experimental; #)Google Scholar
  10. 67Mil:.
    S.C. Miller and W.F. Love,Tables of Irreducible Representations of Space Groups and Co-Representations of Magnetic Space Groups, Pruett Press, Boulder, CO (1967) I24. (Crys Structure; Theory)Google Scholar
  11. 68Mue:.
    W.M. Mueller, J.P. Blackledge, and G.G. Libowitz,Metal Hydrides, Academic Press, New York, NY, Ch 10 (1968). (Thermo; Review)Google Scholar
  12. 70Wea:.
    R.C. Weast, Ed.,Handbook of Chemical Physics, Chemical Rubber Co., Cleveland, OH, pF-152 (1970). (Crys Structure; Review)Google Scholar
  13. 72Bea:.
    A.G. Beattie, “Acoustic Velocity Measurements in the Metal Hydrides ScH1.99, YH1.93, and ErH1.81,”J. Appl. Phys., 43, 3219- 3221 (1972). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  14. 72Mir:.
    N.F. Miron, V.I. Shcherbak, V.N. Bykov, and V.A. Levdik, “Neutron Diffraction Study of Scandium Hydride,”Kristallografiya, 16, 822–823 (1971) in Russian; TR:Sov. Phys. Crystallography, 16, 709-710 (1972). (Crys Structure; Experimental)Google Scholar
  15. 72Wea:.
    H.T. Weaver, “Nuclear-Magnetic-Resonance Investigation of Proton Motion in Scandium Hydride,”Phys. Rev. B, 5, 1663–1667 (1972). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  16. 73Kha:.
    Phys. Status Solidi (b), 60, 9–37 (1973). (Crys Structure; Theory)CrossRefGoogle Scholar
  17. 75Fis:.
    Z. Fisk and D.C. Johnston, “Isotope Effect in the Resistivity of Scandium Hydride,”Phys. Lett., 53A, 39–40 (1975). (Thermo; Experimental)ADSGoogle Scholar
  18. 75Fon:.
    D. de Fontaine, “k-Space Symmetry Rules for Order-Disorder Reactions,”Acta Metall., 23, 553–571 (1975). (Crys Structure; Theory)CrossRefGoogle Scholar
  19. 76Dao:.
    J.N. Daou, A. Lucasson and P. Lucasson, “Electrical Resistivity of the α-Phase Lutetium-Hydrogen at Low Temperature,”Solid State Commun., 19, 895–897 (1976). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  20. 77Boy:.
    J.B. Boyce, J.C. Mikkelsen, and M. O’Keeffe, “Ion Dynamics and Sublattice Melting in the Superionic Conductor PbF2,”Solid State Commun., 21, 955–958 (1977). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  21. 77Ven:.
    E.L. Venturini and B. Morosin, “Low Temperature Anomaly in Sc0.995Gd0.005H1.9,”Phys. Lett. A, 61, 326–328 (1977). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  22. 78Bas1:.
    I.O. Bashkin, E.G. Ponyatovskii, and M.E. Kost, “Phase Transformations in Hydrides of Rare-Earth Metals Under Pressure: II. The Sc-H and Yb-H Systems Under High Hydrogen Pressure,”Phys. Status Solidi (b), 87, 369–372 (1978). (Equi Diagram, Crys Structure; Experimental)CrossRefGoogle Scholar
  23. 78Bas2:.
    I.O. Bashkin, E.G. Ponyatovskii, and M.E. Kost, “P-T Diagram of the System Sc-H at High Hydrogen Pressures,”Izv. Akad. Nauk SSSR, Neorg. Mater., 14, 1615–1616 (1978) in Russian; TR:Inor- ganic Mater., 14, 1260-1261 (1978). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  24. 79Ven:.
    E.L. Venturini and P.M. Richards, “Electron Spin Resonance Determination of Proton Locations in a Hydride,”Solid State Commun., 32, 1185–1188 (1979). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  25. 80Bou:.
    P.C.P. Bouten and A.R. Miedema, “On the Heats of Formation of the Binary Hydrides of Transition Metals,”J. Less-Common Met., 71, 147–160 (1980). (Thermo; Theory)CrossRefGoogle Scholar
  26. 80Jen:.
    C.L. Jensen and M.P. Zalesky, “Electrical Resistivity of Scandium-Hydrogen Alloys from 295 to 4.2 K,”J. Less-Common Met., 75, 197–205 (1980). (Equi Diagram, Crys Structure; Experimental)CrossRefGoogle Scholar
  27. 80Kot:.
    K. Koto, H. Schulz, and R.A. Huggins, “Anion Disorder and Ionic Motion in Lead Fluorite (β-PbF2,”Solid State Ionics, 1, 355–365 1980. (Crys Structure; Experimental)CrossRefGoogle Scholar
  28. 81Her:.
    C. Herrero and F.D. Manchester, Location of the Low Temperature Resistivity Anomaly in Pd-D,”Phys. Lett. A, 86, 29–31 (1981). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  29. 81Kan:.
    K. Kandasamy and N.A. Surplice, “The Effects of Hydrogen on the Resistivity of Some Transition Metals,”Physics of Transition Metals, Conference Series Number 55, Int. Conf. on the Physics of Transition Metals, Leeds, England, 18-22 Aug (1980), The Institute of Physics, Bristol, England, 587–590 (1981). (Equi Diagram; Experimental)Google Scholar
  30. 82Gro:.
    W.A. Grosshans, Y.K. Vohra, and W.B. Holzapfel, “High Pressure Phase Transformations in Yttrium and Scandium: Relation to Rare Earths and Actinides Crystal Structures,”J. Magn. Magn. Mater., 29, 282–286 (1982). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  31. 82San:.
    J.M. Sanchez, D. Gratias, and D. de Fontaine, “Special-Point Ordering in General Crystal Structures,”Acta Crystallogr. A, 38, 214- 221 (1982). (Crys Structure; Theory)CrossRefADSGoogle Scholar
  32. 82Sik:.
    S.K. Sikka, Y.K. Vohra, and R. Chidambaram, “Omega Phase in Materials,”Prog. Mater. Sci., 27, 245–310 (1982). (Crys Structure; Review)CrossRefGoogle Scholar
  33. 82Sur:.
    N.A. Surplice and K. Kandasamy, “The Phase Boundaries of the H-Er, H-Sc and H-Yb Systems at 295K Deduced from Changes of Film Resistance,”J. Phys. D, Appl. Phys., 15, 1117–1124 (1982). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  34. 82Voh:.
    Y.K. Vohra, W. Grosshaus, and W.B. Holzapfel, “High- Pressure Phase Transformation in Scandium,”Phys. Rev. B, 25, 6019- 6021 (1982). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  35. 83Saw:.
    C.K. Saw, B. J. Beaudry, and C. Stassis, “Location of Deuterium in α-Scandium,”Phys. Rev. B, 27, 7013–7017 (1983). (Equi Diagram, Crys Structure; Experimental)CrossRefADSGoogle Scholar
  36. 84Bla:.
    O. Blaschko, “Structural Features Occurring in PdDx within the 50K Anomaly Region,”J. Less-Common Met., 100, 307–320 (1984). (Crys Structure; Experimental)CrossRefGoogle Scholar
  37. 84Gri:.
    R. Griessen and A. Driessen, “Heat of Formation and Band Structure of Binary and Ternary Metal Hydrides,”Phys. Rev. B, 30, 4372–4381 (1984).(Thermo;Theory)CrossRefADSGoogle Scholar
  38. 84Hut:.
    M.T. Hutchings, K. Clausen, M.H. Dickens, W. Hayes, J.K. Kjems, P.G. Schnabel, and C. Smith, “Investigation of Thermally Induced Anion Disorder in Fluorites Using Neutron Scattering Techniques,”J. Phys. C, 17, 3903–3940 (1984). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  39. 85Bla:.
    O. Blaschko, G. Krexner, J.N. Daou, and P. Vajda, “Experimental Evidence of Linear Ordering of Deuterium in α-Lu-Dx,”Phys. Rev. Lett., 55, 2876–2878 (1985). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  40. 85Fuk:.
    Y. Fukai and H. Sugimoto, “Diffusion of Hydrogen in Metals,”Advances in Phys., 34, 263–326 (1985). (Crys Structure; Theory)CrossRefADSGoogle Scholar
  41. 85Kan:.
    K. Kandasamy and N.A. Surplice, “Changes of Resistance, Work Function and Fermi Level During the Hydriding of Zr and Sc at 295 K,”J. Phys. D, Appl. Phys., 18, 1377–1384 (1985). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  42. 86Ake:.
    J.Akella, J. Xu and G.S. Smith, “Static High Pressure Studies on Nd and Sc,”Physica, 139 and l40B, 285-288 (1986). Crys Structure; ExperimentalGoogle Scholar
  43. 86And:.
    I.S. Anderson, J.J. Rush, T. Udovic, and J.M. Rowe, “Hydrogen Pairing and Anisotropic Potential for Hydrogen Isotopes in Yttrium,”Phys. Rev. Lett., 57, 2822–2825 (1986). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  44. 86Dao:.
    J.N. Dao, P. Vajda, A. Lucasson, and J.P. Burger, “Defect Kinetics in Quenched and Electron-Irradiated -ScH(D)x Solid Solutions, ” Phys. Status Solidi A, 95, 543–555 (1986). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  45. 86Gui:.
    A.F. Guillermet, “The Pressure Dependence of the Expansivity and of the Anderson-Grueneisen Parameter in the Murnaghan Approximation,”J. Phys. Chem. Solids, 47, 605–607 (1986). (Thermo; Theory)CrossRefADSGoogle Scholar
  46. 86Mos:.
    A Moss, P.M. Richards, E.L. Venturini, J.H. Gieske, and E.J. Graeber, “Hydrogen Contribution to the Heat Capacity of Single Phase, Face-Centered-Cubic Scandium Deuteride,”J. Chem. Phys., 84, 956–963 (1986). (Thermo; Experimental)CrossRefADSGoogle Scholar
  47. 86Rob:.
    D.S. Robinson, J.L. Zarestky, C. Stassis, and D.T. Peterson, “Neutron Diffraction Study of ScD1.8,”Phys. Rev. B, 34, 7374–7375 (1986). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  48. 87Bar1:.
    R.G. Barnes, F. Borsa, M. Jerosch-Herold, J.W. Han, M. Bel- houl, J. Shinar, D.R. Torgeson, D.T. Peterson, G.A. Styles, and E.F.W. Seymour, “Dynamical Evidence of Hydrogen Sublattice Melting in Metal-Hydrogen Systems,”J. Less-Common Met., 129, 279–285 (1987). (Crys Structure; Experimental)CrossRefGoogle Scholar
  49. 87Bar2:.
    R.G. Barnes, M. Jerosch-Herold, J. Shinar, F. Borsa, D.R. Torgeson, D.T. Peterson, A.J. Lucas, G.A. Styles, and E.F.W. Seymour, “Dynamical Evidence for a Change in Hydrogen-Diffusion Behaviour in Transition-Metal Hydrides at High Temperatures,”Phys. Rev. B, 35, 890–897(1987). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  50. 87Bon:.
    J.E. Bonnet, D.K. Ross, D.A. Faux, and I.S. Anderson, “Long- Range and Short-Range Ordering of Hydrogen or Deuterium Atoms in Solid Solution in Yttrium,”J. Less-Common Met., 129, 287–295 (1987). (Equi Diagram, Crys Structure; Experimental)CrossRefGoogle Scholar
  51. 87Mck:.
    M.W. McKergow, D.K. Ross, J.E. Bonnet, I.S. Anderson, and D. Schaerpf, “One Dimensional Ordering of Deuterium in Solution in Yttrium,”J. Phys. C, 20, 1909–1923 (1987). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  52. 87Wan:.
    Y.B. Wang and D.O. Northwood, “Calculation of the Enthalpy of Metal Hydride Formation,”J. Less-Common Met., 135, 239–245 (1987). (Thermo; Theory)CrossRefGoogle Scholar
  53. 88And:.
    I.S. Anderson, N.F. Berk, J.J. Rush, and T.J. Udovic, “Concentration and Temperature Dependence of Hydrogen Vibrations Along the c-Axis for Hydrogen in Yttrium: Evidence of Dynamically Coupled Hydrogen Pairs,”Phys. Rev. B, 37, 4358–4362 (1988). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  54. 88Kha:.
    D. Khatamian and F.D. Manchester, “The H-Y (Hydrogen- Yttrium) System,”Bull. Alloy Phase Diagrams, 9, 252–260 (1988). (Equi Diagram; Review)CrossRefGoogle Scholar
  55. 88Wan:.
    Y.B. Wang and D.O. Northwood, “Calculation of Enthalpy of Metal Hydride Formation and Prediction of Hydrogen Site Occupancy,”Mater. Sci. Technol., 4, 97–100(1988). (Thermo; Theory)Google Scholar
  56. 89Bla1:.
    O. Blaschko, G. Krexner, J. Pleschiutschnig, G. Ernst, J.N. Daou, and P. Vajda, “Hydrogen Ordering in α-LuDx, Investigated by Diffuse Neutron Scattering,”Phys. Rev. B, 39, 5605–5610 (1989). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  57. 89Bla2:.
    A Blaschko, J. Pleschiutschnig, P. Vajda, J.P. Burger, and J.N. Dao, “Chainlike Hydrogen Ordering in α-ScDx Systems,”Phys. Rev. B, 40, 5344–5349 (1989). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  58. 89Lic:.
    L.R. Lichty, J.W. Han, R. Ibanez-Meier, D.R. Torgeson, R.G. Barnes, E.F.W. Seymour, and C.A. Sholl, “Low-Temperature Localized Motion of Hydrogen and Electronic Structure Transition in Hexagonal-Close-Packed Scandium,”Phys. Rev. B, 39, 2012–2021 (1989). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  59. 89Wat:.
    K. Watanabe, M. Matsuyama, K. Ashida, and H. Miyake, “Alloying Effect on a Property of Hydrogen Gettering Materials: An Empirical Formula to Estimate Heat of Hydride Formation for Metals and Alloys,”J. Vac. Sci. Technol. A, 7, 2725–2729 (1989). (Thermo; Theory)CrossRefADSGoogle Scholar
  60. 91Bar:.
    R.G. Barnes, “NMR Studies of Localized Interstitial Hydrogen Motion in the H.C.P. Metals Sc, Y, and Lu,”J. Less-Common Met., 172–174, 509–521 (1991). (Crys Structure; Experimental)Google Scholar
  61. 91Ber:.
    N.F. Berk, J.J. Rush, T.J. Udovic, and I.S. Anderson, “Anomalous Hydrogen Dynamics in Rare Earth Metals,”J. Less-Common Met., 172–174, 496–508 (1991). (Crys Structure; Experimental)CrossRefGoogle Scholar
  62. 91Bla:.
    O. Blaschko, “Hydrogen Ordering in Metal-Hydrogen Systems,”J. Less-Common Met., 172–174, 237–245 (1991). (Crys Structure; Experimental)Google Scholar
  63. 92Gon:.
    I.N. Goncharenko, V.P. Glazkov, A.V. Irodova, O.A. Lavrova, and V.A. Somenkov, “Compressibility of Dihydrides of Transition Metals,”J. Alloys and Compounds, 179, 253–257 (1992). (Thermo; Experimental)CrossRefGoogle Scholar
  64. 92Lit:.
    L.M. Lityagina and T.I. Dyuzheva, “Isothermal Compression Study of 3d and 4d Transition Metal Dihydrides,”J. Alloys and Compounds, 179, 69–71 (1992). (Thermo; Experimental)CrossRefGoogle Scholar
  65. 92Tra:.
    J. Trampenau, W. Petty, and A. Heiming, “Phonons in the BCC Phase of Sc,”Physica B, 180–181, 363–365 (1992). (Crys Structure; Experimental)CrossRefGoogle Scholar
  66. 93Fai:.
    J.P.A. Fairclough, D.K. Ross, and S.M. Bennington, “Diffuse Neutron Scattering from Yttrium Hydride,”Phys. Chem., 179, 281- 287 (1993). (Crys Structure; Experimental)Google Scholar
  67. 93Lei:.
    V Leisure, R.B. Schwartz, A. Migliori, D.R. Torgeson, and I. Svare, “Hydrogen-Isotope Motion in Scandium Studied by Ultrasonic Measurements,”Phys. Rev. B, 48, 893–900 (1993). (Crys Structure, Thermo ; Experimental)CrossRefADSGoogle Scholar
  68. 93Pet:.
    W. Petry, J. Trampenau, and C. Herzig, “Phonon Dispersion of Beta-Sc,”Phys. Rev.B, 48, 881–886 (1993). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  69. 93Udo:.
    T.J. Udovic, J.J. Rush, N.F. Berk, I.S. Anderson, J.N. Daou, P. Vajda, and O. Blaschko, “Neutron Spectroscopic Comparison of Rare-Earth/Hydrogen α-Phase Systems,”Z. Phys. Chem., 179, 349- 357 (1993). (Crys Structure; Experimental)Google Scholar
  70. 94Bas:.
    I.O. Bashkin, private communication to the authors (1994). (Equi Diagram)Google Scholar
  71. 94Man:.
    F.D. Manchester, A. San-Martin, and J.M. Pitre, “The H-Pd (Hydrogen-Palladium) System,”J. Phase Equilibria, 15, 62–83 (1994). (Crys Structure; Review)CrossRefGoogle Scholar
  72. 95Bar:.
    R.G. Barnes, J-W. Han, D.R. Torgeson, D.B. Baker, M.S. Con- radi, and R.E. Norberg, “Normal and Anomalous Nuclear Spin- Lattice Relaxation at High Temperatures in Sc-H(D), Y-H and Lu-H Solid Solutions,”Phys. Rev. B, 51, 3503–3511 (1995). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  73. 97Man:.
    F.D. Manchester and J.M. Pitre, “The Ce-H (Cerium- Hydrogen) System,” submitted toJ. Phase Equilibria, 18, 63–77 (1997). (Crys Structure; Experimental)CrossRefGoogle Scholar

Copyright information

© ASM International 1997

Authors and Affiliations

  • F. D. Manchester
    • 1
  • J. M. Pitre
    • 1
  1. 1.Centre for Metal Hydride Studies, McLennan Physical LaboratoriesUniversity of TorontoTorontoCanada

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