Homolytic alkylation of succinic anhydride with 1-alkenes

  • Yu. N. Qgibin
  • M. N. Élinson
  • G. I. Nikishin
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Conclusions

The reaction of succinic anhydride with C8−C18-alkenes, initiated by tert-butyl peroxide, leads to the formation of n-alkylsuccinic anhydrides, the yield of which under the optimum conditions is 50–75%.

Keywords

Anhydride Chlorobenzene Octadecene Succinic Anhydride Acetyl Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature Cited

  1. 1.
    G. I. Nikishin, Yu. N. Ogibin, and A. D. Petrov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1487 (1961).Google Scholar
  2. 2.
    A. D. Petrov, G. I. Nikishin, and Yu. N. Ogibin, Dokl. Akad. Nauk SSSR,131, 580, (1960); G. I. Nikishin, Yu. N. Ogibin, and A. D. Petrov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1326 (1961).Google Scholar
  3. 3.
    S. I. Sadykh-Zade, R. I. Mustafaev, and S. D. Yul'chevskaya, Zh. Organ. Khim.,4, 560 (1968).Google Scholar
  4. 4.
    G. I. Nikishin, Yu. N. Ogibin, and I. A Palanuer, Izv. Akad. Nauk SSSR, Ser. Khim. 2478 (1967).Google Scholar
  5. 5.
    Ch. Walling and E. S. Huyser, in: Organic Reactions [Russian translation], Vol. 13, Mir (1966), p. 103; H. Vogel, Synthesis, 99 (1970); J. K. Kochi (editor), Free Radicals, Vol. 2, Wiley, New York (1973), p. 63.Google Scholar
  6. 6.
    V. C. Barry and D. W. Twomey, Proc. Roy. Irish Acad.,51B, 137 (1947).Google Scholar
  7. 7.
    D. E. Ames, and R. E. Bowman, J. Chem. Soc., 1057 (1952).Google Scholar
  8. 8.
    F. Critchfield, Analysis of Basic Functional Groups in Organic Compounds [Russian translation], Mir (1965), p. 183.Google Scholar
  9. 9.
    R. J. W. Le Fevre and A. Sundaram, J. Chem. Soc., 4009 (1962).Google Scholar
  10. 10.
    K. Weygand and G. Hilgetag, Preparative Organic Chemistry, Wiley-Interscience (1972).Google Scholar
  11. 11.
    K. Nakanishi, Infrared Spectra and Structure of Organic Compounds [Russian translation], Mir (1965), p. 56.Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • Yu. N. Qgibin
  • M. N. Élinson
  • G. I. Nikishin

There are no affiliations available

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