The effects of impurity elements on the reduction of wustite and magnetite to iron in CO/CO2 and H2/H2O gas mixtures
Solid State Reactions
Received:
- 289 Downloads
- 25 Citations
Abstract
The reduction of dense wustite and magnetite samples in CO/CO2 and H2/H2O gas mixtures has shown that impurity elements in solid solution in the oxides can significantly affect the reaction mechanisms operative during reduction and the conditions for porous iron growth. In general, the presence of P, Mg, Ti, Si, Ca, K, and Na in wustite favors, in order of increasing strength, the formation of the porous iron product morphology. Aluminum, on the other hand, significantly reduces the range of gas conditions over which the porous iron microstructure may be obtained.
Keywords
Magnetite Metallurgical Transaction Wustite Impurity Element Porous Iron
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
References
- 1.J. Ostwald:BHP Techn. Bull., 1981, vol. 25, pp. 13–20.Google Scholar
- 2.S.C. Panigrahy, P. Verstraeten, and J. Dilewijns:Metall. Trans. B, 1984, vol. 15B, pp. 23–34.Google Scholar
- 3.V.J. Moran and A.E. Jenkins:JISl, 1961, vol. 199, pp. 26–33.Google Scholar
- 4.S.E. Khalafalla and P.L. Weston:Trans. TMS-AIME, 1967, vol. 239, pp. 1494–99.Google Scholar
- 5.R. Piepenbrock, K. Koch, and G. Tromel:Arch. Eisenhuettenwes., 1976, vol. 47, pp. 141–46.Google Scholar
- 6.Y. Iguchi and M. Inouye:Trans. ISIJ, 1982, vol. 22, pp. 678–87.Google Scholar
- 7.M. Moukassi, M. Gougeon, P. Steinmetz, B. Dupre, and C. Gleitzer:Metall. Trans. B, 1984, vol. 15B, pp. 383–91.Google Scholar
- 8.N. Shigamatsu and H. Iwai:Trans. ISIJ, 1985, vol. 25, p. B143.Google Scholar
- 9.H. Nakagawa and Y. Ono:Trans. ISIJ, 1985, vol. 25, pp. 1021–24.Google Scholar
- 10.T. Maeda and Y. Ono:Trans. ISU, 1985, vol. 25, pp. 1191–93.Google Scholar
- 11.F. Nakiboglu, D.H. St. John, and P.C. Hayes:Metall. Trans. B, 1986, vol. 17B, pp. 375–81.Google Scholar
- 12.D.H. St. John, F. Nakiboglu, and P.C. Hayes:Metall. Trans. B, 1986, vol. 17B, pp. 383–93.Google Scholar
- 13.M. Gougeon, B. Dupr’e, and C. Gleitzer:Metall. Trans. B, 1986, vol. 17B, pp. 657–63.Google Scholar
- 14.K. Nishihara, H. Nakagawa, and Y. Ono:Trans. ISU, 1987, vol. 27, p. B142.Google Scholar
- 15.S.X. Dou, A.V. Bradshaw, and S. Blairs:Ironmaking and Steelmaking, 1988, vol. 15, pp. 74–81.Google Scholar
- 16.N. Shigematsu and H. Iwai:Trans. ISIJ, 1988, vol. 28, pp. 206–13.Google Scholar
- 17.S.P. Matthew, D.H. St. John, J.V. Hardy, and P.C. Hayes:Metallography, 1985, vol. 17, pp. 367–79.CrossRefGoogle Scholar
- 18.S.P. Matthew and P.C. Hayes:Metall. Trans. B, 1990, vol. 21B, pp. 153–72.Google Scholar
- 19.S.P. Matthew and P.C. Hayes:Metall. Trans. B, 1990, vol. 21B, pp. 141–52.Google Scholar
- 20.N. Standish and W.K. Lu:Proc. Symp. on Alkalis in Blast Furnaces, McMaster University, Hamilton, ON, Canada, 1973.Google Scholar
- 21.D.H. St. John, S.P. Matthew, and P.C. Hayes:Metall. Trans. B, 1984, vol. 15B, pp. 701–08.Google Scholar
Copyright information
© The Minerals, Metals & Material Society 1990