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Metallurgical Transactions B

, Volume 10, Issue 1, pp 5–14 | Cite as

Carbothermic reduction of domestic chromites

  • Ralph H. Nafziger
  • Jack E. Tress
  • Jack I. Paige
Solid State Reactions

Abstract

Maximizing minerals recovery from domestic resources and minimizing the energy requirements of mineral processing constitute two goals of the Bureau of Mines, U.S. Department of the Interior. Accordingly, the Bureau has determined that coal char is generally the preferred reductant among commercially available carbonaceous materials in laboratory scale reduction experiments in argon between 1100 and 1500°C on a domestic metallurgical grade chromite with respect to the degree of reduction and metallization. For a domestic high iron chromite, coal char is preferred between 1100 and 1300°C, whereas metallurgical coke is the reductant of choice at 1400 and 1500°C. Both domestic chromites display generally similar reduction characteristics. The degrees of reduction and metallization are proportional to the time and/or temperature used and generally the rate of reduction is greatest during the first 15 min. The high iron chromite is more easily reduced, especially at the higher temperatures. Relatively simple kinetic equations cannot adequately describe the reduction mechanism for both chromites. The reduction may be nucleation controlled, especially under conditions of interest to commercial operations. The results could be used as a guideline for prereducing domestic chromites for subsequent smelting operations.

Keywords

Olivine Metallurgical Transaction Chromite Carbothermic Reduction Shell Carbon 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    J. L. Morning: U. S. Bureau of Mines Bulletin 667, pp. 241–52, 1975.Google Scholar
  2. 2.
    K. P. Shaver and S. B. Lasday:Ind. Heating, 1975, vol. 42, no. 1, pp. 10–22.Google Scholar
  3. 3.
    W. A. Scholes:33 Magazine, 1974, vol. 12, no. 12, p. 38.Google Scholar
  4. 4.
    Y. Otani and K. Ichikawa:Proceedings of lNFACON 74, Helen Glen, ed., pp. 31-37, The First International Congress on Ferro-alloys, South African Institute of Mining and Metallurgy, Johannesburg, 1975.Google Scholar
  5. 5.
    W. L. Hunter and D. L. Paulson: U. S. Bureau of Mines Rep. of Investigation 6755,1966,20 pp.Google Scholar
  6. 6.
    N. A. Barcza: Report No. 1365, p. 14, National Institute for Metallurgy, Johannesburg, South Africa, 1972.Google Scholar
  7. 7.
    L. B. McRae:Proc. Second Int. Symp. on Agglomeration, vol. 1, pp. 356–77, SME-AIME, New York, NY, 1977.Google Scholar
  8. 8.
    N. L. Woollacott and J. B. See: Report No. 1950, 24 pp, National Institute for Metallurgy, Randburg, South Africa, 1973.Google Scholar
  9. 9.
    R. C. Urquhart, P. R. Jochens, and D. D. Howat:Proceedings oflNFACON 74, Helen Glen, ed., pp. 195-205, The First International Congress on Ferro- alloys, South African Institute of Mining and Metallurgy, Johannesburg, 1975.Google Scholar
  10. 10.
    R. D. Shannon and C. T. Prewitt:Acta Crystallogr., 1969, vol. B25, part 5, pp. 925–46;Acta Crystallogr., 1970, vol. B26, part 7, pp. 1046-48.Google Scholar
  11. 11.
    L. B. Pankratz: private communication, U. S. Bureau of Mines, Albany Met- allurgy Research Center, Albany, Oregon, 1976.Google Scholar
  12. 12.
    M. A. Qayyum and D. A. Reeve:Can. Met. Quart., 1976, vol. 15, no. 3, pp. 193–200.Google Scholar
  13. 13.
    H. K. Mao and P. M. Bell:Geochim. Cosmochim. Acta, 1975, vol. 39, pp. 865–74.CrossRefGoogle Scholar
  14. 14.
    W. Gomes:Nature, 1961, vol. 192, no. 4805, pp. 865–66.CrossRefGoogle Scholar

Copyright information

© American Society for Metals and the Metallurgical Society of Aime 1979

Authors and Affiliations

  • Ralph H. Nafziger
    • 1
  • Jack E. Tress
    • 1
  • Jack I. Paige
    • 1
  1. 1.Albany Metallurgy Research Center, U. S. Department of the InteriorBureau of MinesAlbany

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