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Metallurgical Transactions B

, Volume 14, Issue 4, pp 577–588 | Cite as

Leaching of bornite in acidified ferric chloride solutions

  • B. Pesic
  • F. A. Olson
Hydrometallurgy

Abstract

In an acidified ferric chloride solution, bornite leaches in two stages of reaction with the first being relatively much more rapid than the second; the first terminates at 28 pct copper dissolution. The first-stage dissolution reaction is electrochemical and is mixed kinetics-controlled; ferric-ion transfer through the solution boundary layer and reduction on the surface to release Cu2+ into solution are both important in controlling the rate. The concentration of labile Cu+ in the bornite lattice governs the potential of the surface reaction, and, once Cu+ is depleted from the original bornite, stage-I reaction ceases. The solid reaction intermediate formed is Cu3FeS4. Minute subcrystallites formed at the latter part of stage I leach topochemically in stage II. This reaction which commences at 28 pct Cu dissolution is characterized by a change in mechanism at about 40 pct copper dissolution, though the overall chemical equation for reaction is unchanged in stage II; cupric and ferrous ions and sulfur as a solid residue are products of reaction. The region 28 to about 40 pct Cu dissolution is designated as a transition period to stage-II reaction. Reaction rate in this period is interpreted as being controlled by reduction of Fe3+ on active product sulfur surface sites, and hence the reaction rate is controlled by the rate of nucleation and growth of sulfur on the Cu3FeS4 intermediate surfaces. Strain in the Cu3FeS4 crystal lattice is released during this period by diffusion from the lattice of Cu+ remaining from the labile copper initially present in the bornite. After about 40 pct Cu dissolution the rate of reaction is controlled by diffusion through the fully formed sulfur layer in an equiaxial geometrically controlled reaction.

Keywords

Metallurgical Transaction Chalcopyrite Salt Lake City Bornite Chalcocite 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© The Metallurgical of Society of AIME 1983

Authors and Affiliations

  • B. Pesic
    • 1
  • F. A. Olson
    • 2
  1. 1.Department of Metallurgical and Mining EngineeringUniversity of IdahoMoscow
  2. 2.University of UtahSalt Lake City

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