Journal of Phase Equilibria

, Volume 12, Issue 5, pp 578–586 | Cite as

The Co-Si (Cobalt-Silicon) system

  • K Ishida
  • T Nishizawa
  • M. E Schlesinger


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Cited References

  1. 34Vog:.
    R. Vogel and K. Rosenthal, “Co-Si Phase Diagram,”Arch. Eisenhüttenwes.,12, 689–691 (1934) in German. (Equi Diagram; Experimental)Google Scholar
  2. 37Has:.
    U. Hashimoto, “The Equilibrium Diagram of the Cobalt- Silicon System,”J. Jpn. Inst. Met.,1, 135–143 (1937) in Japanese. (Equi Diagram, Meta Phases, Crys Structure, Magnetism; Experimental;#)Google Scholar
  3. 37Kos:.
    W. Köster and E Schmid, “Effect of Elements of Be, C and Si on the Polymorphic Transformation of Co,”Z. Metallkd.,29, 232–233 (1937) in German. (Equi Diagram, Meta Phases, Magnetism; Experimental)Google Scholar
  4. 37Oel:.
    W. Oelsen and W. Middel, “Thermochemistry of Alloys I. Determination of the Heats of Formation of the Alloy Systems Cobalt- Silicon, Iron-Aluminum, Cobalt-Aluminum, Nickel-Aluminum, Copper-Aluminum and Antimony-Zinc for the Cast State,”Mitt. Kaiser-Wilhelm Inst. Eisenforsch. Dusseldorf, 19, 1–20 (1937) in Ger- man. (Thermo; Experimental; #)Google Scholar
  5. 55Benl:.
    R. Benoit, “Paramagnetic Study of Binary Compounds,”J. Chim. Phys.,52,119–132 (1955) in French. (Magnetism; Experimental)Google Scholar
  6. 55Ben2:.
    R. Benoit, “The Binding Valence of Some Binary Compounds,”J. Chim. Phys.,52, 201–212 (1955) in French. (Magnetism; Experimental)Google Scholar
  7. 57Col:.
    C.B. Collins and R.O. Carlson, “Properties of Silicon Doped with Iron or Copper,”Phys. Rev.,108, 1409–1414 (1957). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  8. 60Gel:.
    P.V. Geld and Yu.M. Gertman, “The First Heats of Solution of Molten Transition Metals (4 Series) in Liquid Silicon,”Fiz. Metal. Metalloved.,10, 299–300 (1960) in Russian; TR: Phys. Met. Metal- logr., 10(2), 137-139 (1960). (Thermo; Experimental)Google Scholar
  9. 63Kuz:.
    Yu.B. Kuz’ma and E.I. Gladyshevskii, “The Co-Mn-Si System,”Zh. Neorg. Khim.,9,674–682 (1963) in Russian; TR: Russ. J. Inorganic Chem., 9, 373-377 (1963). (Equi Diagram; Experimental)Google Scholar
  10. 63Luo:.
    H. Luo and P. Duwez, “Face-Centered Cubic Cobalt-Rich Solid Solutions in Binary Alloys with Aluminum, Gallium, Silicon, Germanium and Tin,”Can. J. Phys.,41, 758–761 (1963). (Meta Phases, Crys Structure; Experimental)ADSGoogle Scholar
  11. 64Asa:.
    S. Asanabe, D. Shinoda, and Y. Sasaki, “Semimetallic Properties of Co1-xFexSi Solid Solutions,”Phys. Rev.,134, A774-A779 (1964). (Magnetism; Experimental)CrossRefADSGoogle Scholar
  12. 64Bow:.
    P.J. Bowles, H.F. Ramstad, and F.D. Richardson, “Activities of Silicon in Metals and Alloys,”J. Iron Steel Inst.,202,113–121 (1964). (Thermo; Experimental)Google Scholar
  13. 64Kal:.
    G.I. Kalishevich, P.V. Geld, and R.P. Krentsis, “Thermal Capacity, Enthalpy, and Entropy of Cobalt Monosilicide,”Teplofiz. Vys. Temp.,2, 16–20 (1964) in Russian, TR: High Temp., 2, 11-14 (1964). (Thermo, Magnetism; Experimental)Google Scholar
  14. 64Sch:.
    K. Schwerdtfeger and H. Engell, “The Free Enthalpy of Formation of Silicon Dioxide and the Activities of Silicon in Liquid Iron and Cobalt,”Arch. Eisenhüttenwes.,35, 533–540 (1964) in German. (Thermo; Experimental)Google Scholar
  15. 64Zel:.
    L.P. Zelenin, F.A. Siderenko, and P.V. Geld, “Structural Features of e-Phase in the Co-Si System,”Izv. V. U. Z. Tsvetn. Metall.,7(2), 146- 151 (1964) in Russian. (Equi Diagram, Crys Structure; Experimental; #)Google Scholar
  16. 65And:.
    L.P. Andreyeva, F.A. Sidorenko, and P.V. Geld, “Valency States of Atoms in the Monosilicides of Certain 3d-Transition Metals at Low Temperatures,”Fiz. Metal. Metalloved.,19, 784–786 (1965) in Russian; TR: Phys. Met Metallogr., 19(5), 129-131 (1965). (Magnetism; Experimental)Google Scholar
  17. 66Shi:.
    D. Shinoda and S. Asanabe, “Magnetic Properties of Silicides of Iron Group Transition Elements,”J. Phys. Soc. Jpn.,21, 555 (1966). (Magnetism; Experimental)CrossRefADSGoogle Scholar
  18. 67Pan:.
    L.A. Panteleimonov, A.A. Babitsyna, and L.A. Roiter, “Interaction of Cobalt with C02Si,”Vestn. Mosk. Univ., Ser. II, 22(6), 87–89 (1967) in Russian. (Equi Diagram, Crys Structure; Experimental; #)Google Scholar
  19. 68Kall:.
    G.I. Kalishevich, P.V. Geld, and R.P. Krentsis, “Heat Capacities of the Higher Silcides of Vanadium, Cobalt and Nickel between 60 and 300 K,”Zh. Fiz. Khim.,42, 1288–1289 (1968) in Russian; TR: Russ. J. Phys. Chem., 42, 675-676 (1968). (Thermo; Experimental)Google Scholar
  20. 68Kal2:.
    G.L Kalishevich, P.V. Geld, and Yu.V. Putinsev, “High Temperature Changes in the Enthalpy of the Higher Vanadium, Cobalt and Nickel Suicides,”Teplofiz. Vys. Temp.,6, 1003–1006 (1968) in Russian; TR: High Temp., 6, 959-962 (1968). (Thermo; Experimental)Google Scholar
  21. 68Man:.
    L. Martin-Garin, I. Ansara, and P. Desri, “Isothermal Sections of the Systems Ag-Ni-Si and Ag-Co-Si and Activity of Silicon in the Liquid Alloys (Ni, Si) and (Co, Si) at 1580 °C,”C.R. Acad. Sci., Ser. C, 266, 1595–1597 (1968) in French. (Thermo; Experimental)Google Scholar
  22. 70Kra:.
    W. Krajewski, J. Krunger, and H. Winterhanger, “Allotropic Transformation and Thermal Expansion of Cobalt Binary Alloys Between 100 and 800 °C,”Cobalt, 48,120–128 (1970) in German. (Meta Phases; Experimental)Google Scholar
  23. 70Kre:.
    R.P. Krentsis, V.Y. Zinovyev, L.P. Andreyeva, and P.V. Geld, “Thermal Diffusivity and Conductivity of Solid Solutions of Silicon in Iron and Cobalt,”Fiz. Met. Metalloved.,29(1), 118–123 (1970) in Russian; TR: Phys. Met. Metallogr., 29(1), 122-127 (1970). (Thermo, Magnetism; Experimental)Google Scholar
  24. 71Pet:.
    M.S. Petrushevskii and P.V. Geld, “Interatomic Interaction Energy and Heat of Mixing in Molten Cobalt-Silicon Alloys,”Izv. V.U.Z. Chem. Metall.,14(10), 9–12 (1971) in Russian. (Thermo; Theory)Google Scholar
  25. 71 Wal:.
    F. Wald and S. J. Michalik, “Ternary System Co-Ge-Si,”J. Less- Common Met.,24, 277–289 (1971). (Crys Structure; Experimental)CrossRefGoogle Scholar
  26. 72Ama:.
    A. Amamou, P. Bach, F. Gautier, and C. Robert, “Measures of Specific Heat and Susceptibility and NMR of CoSi Around Stoichiometry,”J. Phys. Chem. Solids, 33, 1697–1712 (1972) in French. (Magnetism; Experimental)CrossRefADSGoogle Scholar
  27. 72Boo:.
    J.V.D. Boomgaard and F.M.A. Carpay, “The Eutectoid C03Si Phase in the Co-Si System,”Acta MetalL, 20, 473–476 (1972). (Equi Diagram, Meta Phases; Experimental)CrossRefGoogle Scholar
  28. 72Fro:.
    A.A. Frolov, Y.V. Putintsev, F.A. Sidorenko, P.V. Geld, and R.P. rentsis, “Special Features of the Crystallization of Ni2Si and Co2Si and Some Characteristics of These Compounds,”Izv. Akad. Nauk SSSR,Neorg. Mater.,8, 468–411(1971) in Russian;TR:Inorg. Mater., 8, 408-411 (1972). (Equi Diagram, Crys Structure, Thermo; Experimental)Google Scholar
  29. 73Cha:.
    T.G. Chart, “Thermochemical Data for Transition Metal-Silicon Systems,”High Temp.—High Pressures, 5, 241–252 (1973). (Thermo; Review)Google Scholar
  30. 73Joh:.
    R.E. Johnson, H.W. Rayson, and W. Wright, “Structure and Magnetic Properties of Phases Occurring in a Cobalt Silicon Alloy of Eutectic Composition,”Acta Metall.,21, 1471–1477 (1973). (Equi Diagram, Meta Phases, Crys Structure, Magnetism; Experimental)CrossRefGoogle Scholar
  31. 73Kos:.
    W. Koster, H. Warlimont, and T. Godecke, “The System Cobalt-Co2Si,”Z. Metallkd.,64, 399–405 (1973) in German. (Equi Diagram, Meta Phases, Crys Structure, Magnetism; Experimental)Google Scholar
  32. 74Boo:.
    J.V.D. Boomgaard and F.M. Carpay, “On the Existence of a Metastable Eutectic Between Co and Co2Si,”Scr. Metall.,8, 23–26 (1974). (Meta Phases; Experimental)CrossRefGoogle Scholar
  33. 74Man:.
    K. Marklund, M. Larsson, S. Bystrom, and T. Lindqvist, “The Specific Heat of the Binary Compounds FeSi, CoSi, FeGe and CoGe,”Phys. Scr.,9, 47–50 (1974). (Thermo; Experimental)CrossRefGoogle Scholar
  34. 75Dov:.
    S.P. Dovgopol, V.A. Antropov, I.Z. Radovskii, and P.V. Geld, “Magnetic Susceptibility and Electronic Structure of Co-Si and CoGe Alloys at High Temperatures,”Phys. Status Solidi, (b), 70, 439- 449 (1975). (Magnetism; Experimental)CrossRefGoogle Scholar
  35. 75Liv:.
    J.D. Livingston, “Properties of Aligned Co-Si Eutectoid,” Acta Metall.,23, 521–527 (1975). (Meta Phases, Magnetism; Experimental) 76Liv: J.D. Livingston, “Aligned Co-Co2Si Eutectics,” J. Mater. Sci., 11, 246-250 (1976). (Equi Diagram; Experimental)CrossRefGoogle Scholar
  36. 77Kit:.
    H. Kitagawa and K. Hashimoto, “Solid Solubility of Cobalt in Silicon,”Jpn. J. Appl. Phys.,16, 857–858 (1977). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  37. 79Gur:.
    G.J.V. Gurp, G.E J. Eggermont, Y. Tamminga, W.T. Stacy, and J.R.M. Gijsbers, “Cellular Structure and Suicide formation in Laser- Irradiated Metal-Silicon Systems,”Appl. Phys. Lett.,35, 273–275 (1979). (Meta Phases; Experimental)CrossRefADSGoogle Scholar
  38. 79Ind:.
    G. Inden, “Determination of the Interchange Energies WCoSi(l), WCoSi(2) for B.C.C Solid Solutions from High Temperature Neutron Diffraction on Ternary Fe-Co-Si Crystals,”Phys. Status Solidi, (a), 56, 177–186 (1979). (Thermo; Theory)CrossRefGoogle Scholar
  39. 79Kau:.
    L. Kaufman, “Coupled Phase Diagrams and Thermochemical Data for Transition Metal Binary Systems-VI,”Calphad, 3, 45–76 (1979). (Thermo; Theory)CrossRefGoogle Scholar
  40. 79Nie:.
    H.J.V. Nielsen, “An Estimate of the Glass Transition Temperature of Transition Metals Alloyed with Metalloids,”Z. Metallkd.,70, 606–608 (1979). (Meta Phases; Theory)Google Scholar
  41. 80Khal:.
    S.N. Khanna, F. Cyrot-Lackmann, and P. Hicter, “Electronic Contribution to the Entropy of Mixing of Liquid Transition Metal Based Alloys,”J. Phys.,41(C8), 582–585 (1980). (Thermo; Theory)Google Scholar
  42. 80Kha2:.
    S.N. Khanna and F. Cyrot-Lackmann, “On the Entropy of Mixingof Liquid Transition Metal Based Alloys,”J. Chem. Phys.,73, 4636–4639 (1980). (Thermo; Theory)CrossRefADSGoogle Scholar
  43. 80Sai:.
    S. Saitoh, H. Ishiwara, and S. Furukawa, “Double Heteroepitaxy in the Si (111)/CoSi2/Si Structure,”Appl. Phys. Lett.,37, 203–205 (1980). (Meta Phases; Experimental)CrossRefADSGoogle Scholar
  44. 81Mac:.
    E.S. Machlin, “Correction Terms to Pair Potential Model Values of the Energy of Formation for Transition Element-Polyvalent Element Phases,”Calphad, 5, 1–17 (1981). (Thermo; Theory)CrossRefGoogle Scholar
  45. 81Zai:.
    V.K. Zaizev, M.I. Fedorov, and A.Yu. Zyuzin, “On the Figure of Merit of Cobalt Monosilicide-Based Materials,”Geliotekh.,17(4), 18–21 (1981) in Russian; TR: Appl. Solar Energy, 17(4), 17-21 (1981). (Magnetism; Experimental)Google Scholar
  46. 82Lar:.
    V.I. Larchev and S.V. Popova, “The New Chimney-Ladder Phases Co2Si3 and Re4Ge7 Formed by Treatment at High Temperatures and Pressures,”J. Less-Common Met.,84, 87–91 (1982). (Meta Phases, Crys Structure; Experimental)CrossRefGoogle Scholar
  47. 82Sor:.
    Y. Sorimachi, H. Ishiwara, H. Yamamoto, and S. Furukawa, “Electrical and Structural Properties of Ion-Implanted and Post-Annealed Suicide Films,”Jpn. J. Appl. Phys.,21, 752–756 (1982). (Meta Phases; Experimental)CrossRefADSGoogle Scholar
  48. 83Nis:.
    T. Nishizawa and K. Ishida, “The Co (Cobalt) System,”Bull. Alloy Phase Diagrams, 4(4), 387–390 (1983). (Crys Structure; Review)CrossRefGoogle Scholar
  49. 83Pas:.
    A. Pasturel, P. Hicter, D. Mayou, and F. Cyrot-Lackmann, “An Estimation of the Thermodynamic Data of Liquid Transition Metal Based Alloys,”Scr. Metall.,17, 841–846 (1983). (Thermo; Theory)CrossRefGoogle Scholar
  50. 84Hen:.
    J.C. Hensel, R.T. Tung, J.M. Poate, and F.C. Unterwald, “Electrical Transport Properties of CoSi and NiSi2 Thin Films,”Appl. Phys. Lett.,44, 913–915 (1984). (Magnetism; Experimental)CrossRefADSGoogle Scholar
  51. 84Pas:.
    A. Pasturel, P. Hicter, and F. Cyrot-Lackmann, “On the Heats of Formation of Solid Germanides and Silcides of Transition Metals,”Physica B+C,124B, 247–250 (1984). (Thermo; Theory)CrossRefGoogle Scholar
  52. 85Fro:.
    M.G. Frohberg and S. Anik, “Thermodynamic Relations Between Compound Activities and Gas Solubilities on Binary Metallic Systems,”Ber. Bunsenges. Phys. Chem.,89, 130–134 (1985). (Thermo; Theory)Google Scholar
  53. 86Apr:.
    G. Aprilesi, E. Mazzega, M. Michelini, and F. Nava, “Electrical Transport Properties in Co-Silicides Formed by Thin-Film Reactions,”J. Appl. Phys.,60, 310–317 (1986). (Meta Phases, Crys Structure; Experimental)CrossRefADSGoogle Scholar
  54. 87Nav:.
    F. Nava, K.N. Tu, E. Mazzega, M. Michelini, and G. Queirolo, “Electrical Transport Properties of Transition-Metal Disilicide Films,”J. AppL Phys.,61, 1085–1093 (1987). (Magnetism; Experimental)CrossRefADSGoogle Scholar
  55. 87Wei:.
    F. Weitzer and J.C. Schuster, “Phase Diagrams of the Ternary Systems Mn, Fe, Co, Ni-Sn-N,”J. Solid State Chem.,70, 178–184 (1987). (Crys Structure; Experimental)CrossRefADSGoogle Scholar
  56. 88Kim:.
    H.J. Kim, I.K. Kang, and J.S. Chun, “Glass Forming Ranges of Cobalt-Base Thin Film Alloys,”J. Mater. Sci, 23, 4165–4170 (1988). (Meta Phases; Experimental)CrossRefGoogle Scholar
  57. 88Lik:.
    L.S. Iikhoded and L.A. Dvorina, “Formation of a Solid Solution in the System Co-Si,”Izv.Akad.NaukSSSR, Met., (2), 197–199(1988) in Russian; TR: Russ. Met., (2), 188–190 (1988). (Equi Diagram; Experimental)Google Scholar
  58. 88Nie:.
    A.K. Niessen, A.R. Miedema, F.R. de Boer, and R. Boom, “Enthalpies of Formation of Liquid and Solid Binary Alloys on 3d Metals. TV. Alloys of Cobalt,”Physica B, 151, 401–432 (1988). (Thermo; Theory; #)CrossRefGoogle Scholar
  59. 90Eno:.
    H. Enoki, K. Ishida and T. Nishizawa, “Phase Equilibria in Co- rich Portions of the Co-Si and Co-Ge Systems,”J. Less-Common Met.,160, 153–160 (1990). (Equi Diagram; Experimental; #)CrossRefGoogle Scholar

Copyright information

© ASM International 1991

Authors and Affiliations

  • K Ishida
    • 1
  • T Nishizawa
    • 1
  • M. E Schlesinger
    • 2
  1. 1.Tohoku UniversityJapan
  2. 2.University of Missouri-RollaUSA

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