Determination of isothermal sections of nickel rich portion of Ni-Cr-Mo system by analytical electron microscopy
- 308 Downloads
- 51 Citations
Abstract
Ternary sections at 1523 K (1250 °C) and 1123 K (850 °C) of the nickel rich portion of the Ni-Cr-Mo system were determined by analytical electron microscopy (AEM) consisting of X-ray microanalysis and Convergent Beam Diffraction (CBD). At 1523 K, both the gamma solvus boundary and the type of intermetallic (delta, P, and sigma) phases present were in good agreement with some of the previous investigations. However, the three-phase fields were clearly defined only by AEM. At 1123 K, the gamma phase exhibited decreased solubility of Cr and Mo, as expected, but interestingly, the formation of a fourth intermetallic, mu phase, was observed along with the delta, P, and sigma phases. The CBD analyses of thesephases and comparison of the results of the present investigation with the published experimental and theoretical diagrams are presented.
Keywords
Austenite Metallurgical Transaction Isothermal Section Intermetallic Phase Analytical Electron MicroscopyPreview
Unable to display preview. Download preview PDF.
References
- 1.R.G. Barrows and J.B. Newkirk:Metallography, 1972, vol. 5, p. 515.CrossRefGoogle Scholar
- 2.J. D. Hanawalt, H. W. Rinn, and L. K. Frevel:Chemical Analysis by X-RayDiffraction, Ind. Eng. Chem. Anal. Ed., 1938, vol. 10, p. 457.CrossRefGoogle Scholar
- 3.J. Chipman:Metall. Trans., 1972, vol. 3, p. 55.Google Scholar
- 4.E. Butchers, G. V. Raynor, and W. Hume-Rothery:J. Inst. Metals, 1943, vol. 69, p. 209.Google Scholar
- 5.J. Bentley, N. J. Zaluzec, E. A. Kenik, and R. W. Carpenter:Scanning Electron Microscopy, 1979, vol. 2, p. 581.Google Scholar
- 6.J. I. Goldstein and D. B. Williams:Scanning Electron Microscopy, 1977, vol. 1, p. 651.Google Scholar
- 7.N.J. Zaluzec:Introduction to Analytical Electron Microscopy, J.J. Hren, J.I. Goldstein, and D.C. Joy, eds., Plenum Press, New York, NY, 1979, p. 121.Google Scholar
- 8.D.B. Williams: “Microanalysis,”Norelco Reporter, published by Philips Electronic Instruments, Inc., 85 McKee Drive, Mahwah, NJ 07430, 1982, vol. 29, no. 3.Google Scholar
- 9.D. S. Bloom and N.J. Grant:Trans. AIME, 1954, vol. 200, p. 261.Google Scholar
- 10.S. Rideout, W.D. Manley, E.L. Kamen, B.S. Lement, and P.A. Beck:Trans. AIME, 1951, vol. 191, p. 872.Google Scholar
- 11.G. Cliff and G.W. Lorimer:Journal of Microscopy, 1975, vol. 103, p. 203.Google Scholar
- 12.J.W. Steeds:Introduction to Analytical Electron Microscopy, J.J. Hren, J.I. Goldstein, and D.C. Joy, eds., Plenum Press, New York, NY, 1979, p. 387.Google Scholar
- 13.M. Raghavan, J.Y. Koo, and R. Petkovic-Luton:J. Metals, 1983, vol. 35, no. 6.Google Scholar
- 14.D. B. Williams: “Microdiffraction,”Norelco Reporter, published by Philips Electronic Instruments, Inc., 85 McKee Drive, Mahwah, NJ 07430, 1983, vol. 30, no. 2.Google Scholar
- 15.J. I. Goldstein, J. L. Costley, G. W. Lorimer, and S. J. B. Reed:Scanning Electron Microscopy, Illinois Institute of Technology Research Institute, 1977, vol. 1, p. 315.Google Scholar
- 16.C.B. Shoemaker and D.P. Shoemaker:Acta Cryst., 1963, vol. 16, p. 997.CrossRefGoogle Scholar
- 17.J. W. Steeds and N. S. Evans:Proc. Elec. Micros. Soc. Amer., G. W. Bailey, ed., Claitors Publishing Company, Baton Rouge, LA, 1980, p. 188.Google Scholar
- 18.D.P. Shoemaker, C.B. Shoemaker, and F.C. Wilson:Acta Cryst., 1957, vol. 10, p. 1.CrossRefGoogle Scholar
- 19.E.O. Hall and S.H. Algie:Metall. Rev., 1966, vol. 11, p. 61.Google Scholar
- 20.ASM Metals Handbook, Eighth Ed., American Society for Metals, Metals Park, OH, 1973, vol. 8, p. 426.Google Scholar
- 21.L. Kaufman and H. Nesor:Metall. Trans., 1974, vol. 5, p. 1617.Google Scholar
- 22.M. E. Nicholson, C. H. Samans, and F. J. Shortsleeve:Trans. ASM, 1951, vol. 44, p. 601.Google Scholar
- 23.R.G. Barrows and J.B. Newkirk:Metall. Trans., 1972, vol. 3, p. 2889.Google Scholar
- 24.R. B. Leonard:Corrosion, 1969, vol. 25, p. 222.Google Scholar
- 25.F.G. Hodge and R.W. Kirchner:Corrosion, 1976, vol. 32, p. 332.Google Scholar
- 26.M. Raghavan, B. J. Berkowitz, and J. C. Scanion:Metall. Trans. A, 1982, vol. 13A, p. 979.Google Scholar
- 27.A.D. Romig and J.I. Goldstein:Metall. Trans. A, 1980, vol. 11A, p. 1151.Google Scholar