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Journal of the American Oil Chemists Society

, Volume 36, Issue 10, pp 450–453 | Cite as

Derivatives of ricinelaidic acid. Their infrared spectra and conformation of the ricinelaidic moiety

  • Marian A. McCutchon
  • R. T. O’Connor
  • Elsie F. DuPre
  • L. A. Goldblatt
  • W. G. Bickford
Technical

Summary

The infrared spectra and absorptivities in the 10.3 micron region have been determined for a series of compounds in which the functional groups of ricinelaidic acid were varied systematically. The compounds investigated included ricinelaidic acid, 12-ketoelaidic acid, ricinelaidyl alcohol, and their respective methyl esters and acetates. The influence of the internal substitutents on the fundamental absorption pattern of ricinelaidic acid was determined. Observed decreases in molecular absorptivities and shifts in position of maximum absorption are related to the electron-with-drawing character of relevant substituents and to hydrogen bonding in thebeta-hydroxy-ene system. The comormation of this system is discussed.

Keywords

Elaidic Acid Oleyl Alcohol Methyl Elaidate Anhydrous Calcium Sulfate Molecular Absorptivity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© The American Oil Chemists’ Society 1959

Authors and Affiliations

  • Marian A. McCutchon
    • 1
  • R. T. O’Connor
    • 1
  • Elsie F. DuPre
    • 1
  • L. A. Goldblatt
    • 1
  • W. G. Bickford
    • 1
  1. 1.Southern Regional Research LaboratoryNew Orleans

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