Advertisement

Journal of Chemical Crystallography

, Volume 27, Issue 7, pp 397–400 | Cite as

Crystal structure of a silver(I) complex with the 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid)

  • F. Jaber
  • F. Charbonnier
  • R. Faure
Article

Abstract

The reaction between freshly precipitated silver oxide Ag2O and an aqueous solution of tetrabenzenecarboxylic acid H4L leads to the anhydrous Ag2H2L complex. It crystallizes in the space groupP21/c, witha=6.457(1),b=8.180(1),c=9.982(1) Å, β=97.83(1)°,V=522.3(1) Å3,Z=2,d=2.976 g cm−3. This structure is a three dimensional polymeric network polymer without any silver...silver interaction. The silver environment is a bipyramid trigonal polyhedron with three short bond distances in the equatorial plane (Ag−O=2.255(2), 2.295(2), and 2.499(2) Å) and two longer bond distances in axial positions (Ag−O=2.558(2) and 2.617(2) Å). Thus, the silver polyhedron involves five different ligands. It is noteworthy that the (H2L2)2− ligand is located around an inversion centre.

Key Words

Silver(I) 1,2,4,5-benzenetetracarboxylic pyromellitic 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Mak, T.C.W.; Yip, W.H.; Kennard, C.H.L.; Smith; G., O'Reilley, E.J.Aust. J. Chem. 1986,39, 541.CrossRefGoogle Scholar
  2. 2.
    SDP Structure Determination Package; Frenz, B.A. & Associates Inc.: College Station, Tx,1982.Google Scholar
  3. 3.
    Charbonnier, F.; Faure; R.; Loiseleur, H.Acta Crystallogr. 1981,B37, 822.Google Scholar
  4. 4.
    Ward, D.L.; Luehrs, D.C.Acta Crystallogr. 1983,C39, 1370.Google Scholar
  5. 5.
    Jessen, S.M.; Küppers, H.; Luhers, D.C.Z. Naturforsch. 1992,47B, 1141.Google Scholar
  6. 6.
    Jessen, S.M.; Küppers, H.Acta Crystallogr. 1990,C46, 2351.Google Scholar
  7. 7.
    Robl, C.Z. Naturforsch. 1988,43B, 993.Google Scholar
  8. 8.
    Robl, C. Hentschel, S.Mater. Res. Bull. 1991,26, 1355.CrossRefGoogle Scholar
  9. 9.
    Cousson, A.; Stout, B.; Nectoux, F.; Pagès, M.; Gaspein, M.J. Less-Common Met.,1986,125, 111.CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • F. Jaber
    • 1
  • F. Charbonnier
    • 1
  • R. Faure
    • 1
  1. 1.Chimie Analytique 2, LICAS, Bâtiment 305Université Claude Bernard Lyon 1Villeurbanne CedexFrance

Personalised recommendations