Journal of Chemical Crystallography

, Volume 27, Issue 4, pp 247–250

Crystal structure of (2,2′-bipyrimidine)-dinitratopalladium(II) acetone solvate

  • Tony Hudgens
  • Dale Johnson
  • Wallace Cordes
  • Tosha Barclay
  • David Jeter
Article

Abstract

(2,2′-bipyrimidine)dinitratopalladium(II) forms a triclinic crystal in space groupP−1 witha=7.605(5) Å,b=8.791(4) Å,c=12.632(5) Å, α=85.11(3)0, β=78.79(4)0, γ=77.45(4)0,V=807.7(7) Å3, andZ=2. The Pd atom exhibits square planar coordination geometry with mean Pd−O=2.206(7) Å, Pd−N=1.990(5) Å, O−Pd−O=92.0(2)0, and N−Pd−N=81.0(2)0. The complexes associate across an inversion center with Pd...Pd=3.190(2) Å. The bipyrimidine ligand is bowed with a 5.9(2)0 dihedral angle between the C4N2 rings. The nitrate ions are on the same side of the N2O2 donor atoms plane and make 60.4(2)0 and 66.6(2)0 dihedral angles with that plane.

Key words

Palladium bipyrimidine nitrate square planar structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Data collection by Enraf-Nonius CAD4/PC Software, version 1.5c,1994; Data reduction and refinement by NRCVAX/PC: Gabe, E.J.; LePage, Y; Charland, F.L.; White, P.S.J. Appl. Cryst. 1989,22, 383.Google Scholar
  2. 2.
    Langs, D.A.; Hare, C.R.; Little, R.G.Chem. Commun. 1967, 1080.Google Scholar
  3. 3.
    Törnroos, K.W.,Acta Crystallogr. 1995,C51, 238.Google Scholar
  4. 4.
    Izatt, R.M.; Wu, H.; Jiang, W.; Dalley, N.K.Inorg. Chem. 1990,29, 3828.CrossRefGoogle Scholar
  5. 5.
    Suzuki, Y.; Miyamoto, T.K.; Ichida, H.,Acta Crystallogr. 1993,C49, 1318.Google Scholar
  6. 6.
    Faulmann, C.; Legros, J.P.; Cassoux, P.; Cornelissen, J.; Brossard, L.; Inokuchi, M.; Tajima, H.; Tokumoto, M.J. Chem. Soc., Dalton Trans. 1994, 249.Google Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • Tony Hudgens
    • 1
  • Dale Johnson
    • 1
  • Wallace Cordes
    • 1
  • Tosha Barclay
    • 1
  • David Jeter
    • 1
  1. 1.Department of Chemistry and BiochemistryUniversity of ArkansasFayetteville

Personalised recommendations