International Journal of Thermophysics

, Volume 18, Issue 5, pp 1237–1248

A compact photon-correlation spectrometer for research and education

  • I. K. Yudin
  • G. L. Nikolaenko
  • V. I. Kosov
  • V. A. Agayan
  • M. A. Anisimov
  • J. V. Sengers
Article

Abstract

A compact photon-correlation spectrometer for basic and applied research in physics, chemistry, biology, medicine, engineering, and environmental technology as well as for educational laboratory courses in these subjects has been developed. The instrumental setup enables one to make absolute measurements of the sizes of particles suspended in liquids in the range from 0.001 to 5 μm. The measurements are fast, lasting usually from seconds to several minutes. Real-time size monitoring, such as of kinetic aggregation processes, is also possible. The optical arrangement of the spectrometer even makes it possible to measure light scattering in opaque systems which are characterized by strong light absorption. The quantity of the sample to be studied can be quite small, starting from 0.01 cm3. The system includes specially designed software for performing data interpretation and for implementing fitting procedures, for exchange of data with other programs, and for automation of measurements of long duration or of sequences of measurements. Measurements verifying the accuracy of the system are presented for latex suspensions, for aniline dye dissolved in water, and for dilute solutions of polystyrene in toluene.

Key Words

diffusion light scattering liquid mixtures particle sizes photon-correlation spectroscopy viscosity 

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References

  1. 1.
    T. Allen,Particle Size Measurement, 4th ed. (Chapman & Hall, New York, 1990).Google Scholar
  2. 2.
    B. Chu,Laser Light Scattering, 2nd ed. (Academic Press, Boston, 1991).Google Scholar
  3. 3.
    H. Z. Cummins and E. R. Pike (eds.),Photon Correlation and Light Beating Spectroscopy (Plenum, New York, 1974).Google Scholar
  4. 4.
    H. Z. Cummins and E. R. Pike (eds.),Photon Correlation Spectroscopy and Velocimetry (Plenum, New York, 1977).Google Scholar
  5. 5.
    B. J. Berne and R. Pecora,Dynamic Light Scattering with Applications to Chemistry, Biology and Physics (Wiley, New York, 1976).Google Scholar
  6. 6.
    V. Degiorgio, M. Corti, and M. Giglio, (eds.),Light Scattering in Liquids and Macromolecular Solutions (Plenum, New York, 1980).Google Scholar
  7. 7.
    S. H. Chen, B. Chu, and R. Nossal (eds.),Scattering Techniques Applied to Supramolecular and Nonequilibrium Systems (Plenum, New York, 1981).Google Scholar
  8. 8.
    G. S. Gorelik,Dokl. Acad. Nauk SSSR 58:45 (1947).Google Scholar
  9. 9.
    A. T. Forrester, R. A. Gudmundsen, and P. O. Johnson,Phys. Rev. 99:1691 (1955).CrossRefADSGoogle Scholar
  10. 10.
    A. T. Forrester,J. Opt. Soc. Am. 51:253 (1961).CrossRefADSGoogle Scholar
  11. 11.
    R. Pecora,J. Chem. Phys. 40:1604 (1964).CrossRefADSGoogle Scholar
  12. 12.
    H. Z. Cummins, N. Knaple, and Y. Yeh,Phys. Rev. Lett. 12:150 (1964).CrossRefADSGoogle Scholar
  13. 13.
    N. C. Ford, Jr., and G. B. Benedek,Phys. Rev. Lett. 15:649 (1965).CrossRefADSGoogle Scholar
  14. 14.
    S. S. Alpert, inCritical Phenomena, M. S. Green and J. V. Sengers, eds. (National Bureau of Standards Miscellaneous Publication 273, U.S. Government Printing Office, Washington, DC, 1966), p. 157.Google Scholar
  15. 15.
    R. Foord E. Jakeman, C. J. Oliver, E. R. Pike, R. J. Blagrove, E. Wood, and A. R. Peacock,Nature 227:242 (1969).CrossRefADSGoogle Scholar
  16. 16.
    V. I. Labko, V. V. Nikitin, G. L. Nikolaenko, and I. K. Yudin,Proc. “Optika-88” Budapest 2:408 (1988).Google Scholar
  17. 17.
    M. A. Anisimov, I. A. Dmitrieva, and I. K. Yudin,Zh. Prikl. Spektr. 49:144 (1988) (in Russian).Google Scholar
  18. 18.
    C. F. Bohren and D. R. Huffman,Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983).Google Scholar
  19. 19.
    M. A. Anisimov, I. K. Yudin, V. V. Nikitin, G. L. Nikolaenko, A. I. Chernoutsan, H. Toulhoat, D. Frot, and Y. Briolant,J. Phys. Chem. 99:9576 (1995).CrossRefGoogle Scholar
  20. 20.
    K. J. Zhang, M. E. Briggs, J. V. Sengers, R. W. Gammon, and J. F. Douglas, in press.Google Scholar
  21. 21.
    K. J. Zhang, Ph.D. dissertation (Institute for Physical Science and Technology, University of Maryland, College Park, 1996).Google Scholar
  22. 22.
    K. J. Zhang, M. E. Briggs, R. W. Gammon, and J. V. Sengers,J. Chem. Phys. 164: 6881 (1996).CrossRefADSGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • I. K. Yudin
    • 1
  • G. L. Nikolaenko
    • 1
  • V. I. Kosov
    • 1
  • V. A. Agayan
    • 2
  • M. A. Anisimov
    • 2
  • J. V. Sengers
    • 2
    • 3
  1. 1.Laboratory for Phase Transitions and Critical PhenomenaOil & Gas Research Institute of the Russian Academy of SciencesMoscowRussia
  2. 2.Institute for Physical Science and TechnologyUniversity of MarylandCollege ParkUSA
  3. 3.Department of Chemical EngineeringUniversity of MarylandCollege ParkUSA

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