Journal of radioanalytical chemistry

, Volume 2, Issue 3–4, pp 243–253 | Cite as

Preparation of Carrier-Free Radionuclides from Cyclotron Targets by Continuous Electrophoresis, I

Separation of 55Fe from Mangenese, 54Mn and 56,57,58Co from Iron, 65Zn from Copper, and 109Cd from Silver Target
  • Ž. Proso
  • Z. Pučar
Article
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Received:

Abstract

Continuous electrophoretic separation of the components of the manganese, iron, copper and silver cyclotron targets bombarded with deuterons is described. The rates of separation were: managanese target, 4.4 mg Mn/hr; iron target, 1.5 mg Fe/hr; copper target, 1.7 mg Cu/hr; and silver target, 6.7 mg Ag/hr. The radionuclides were separated in carrier-free form and were of high radiochemical purity. The results are represented by radioautographs of the continuous electrophoretic processes, and by diagrams showing the distribution of the target material and of radioactivity along the collecting glasses. The radiochemical purity of the separated radionuclides was checked by the gamma spectra, by estimation of the beta-energies, and by evaluation of the decay curves.

Keywords

Lactic Acid Oxalic Acid Electrical Field Strength Supporting Electrolyte Target Material 
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References

  1. 1.
    Z. Pučar,J. Chromatogr., 4 (1960) 261;Chromatogr. Rev., 3 (1961) 38.CrossRefGoogle Scholar
  2. 2.
    R. A. Bailey, L. Yaffe,Chromatogr. Rev., 3 (1961) 158.CrossRefGoogle Scholar
  3. 3.
    R. A. Bailey, USAEC, NAS-NS 3106, 1962.Google Scholar
  4. 4.
    Z. Konrad-Jakovac, Proc. Radiochem., Conf. Liblice 1964, p. 74.Google Scholar
  5. 5.
    T. R. Sato, W. P. Norris, H. H. Strain,Anal. Chem., 26 (1954) 267.CrossRefGoogle Scholar
  6. 6.
    Z. Pučar, Z. Jakovac,J. Chromatog., 3 (1960) 477.CrossRefGoogle Scholar
  7. 7.
    Z. Konrad-Jakovac, Z. Pučar,J. Chromatog., 7 (1962) 380.CrossRefGoogle Scholar
  8. 8.
    Z. Pučar, Z. Konrad-Jakovac,J. Chromatog., 9 (1962) 106.CrossRefGoogle Scholar
  9. 9.
    V. P. Shvedov, A. V. Stepanov,Radiokhimiya, 1 (1959) 112.Google Scholar
  10. 10.
    V. P. Shvedov, K. A. Stepanov,Radiokhimiya, 2 (1960) 65.Google Scholar
  11. 11.
    V. P. Shvedov, K. A. Peterzhak, R. V. Sedletskii, A. V. Stepanov,Radiokhimiya, 2 (1960) 711.Google Scholar
  12. 12.
    T. R. Sato, W. P. Norris, H. H. Strain,Anal. Chem., 24 (1952) 776.CrossRefGoogle Scholar
  13. 13.
    M. Lederer,Anal. Chim. Acta, 11 (1954) 145.CrossRefGoogle Scholar
  14. 14.
    V. P. Shvedov, A. P. Stepanov, N. I. Gorskii,Radiokhimiya, 5 (1963) 690.Google Scholar
  15. 15.
    Z. Konrad-Jakovac, Z. Pučar,Croat. Chem. Acta, 33 (1961) 33.Google Scholar
  16. 16.
    E. Palmer,Z. Electrochem., 38 (1932) 10.Google Scholar
  17. 17.
    Komplexometrische Bestimmungsmethoden mit Titriplex, E. Merck AG, Darmstadt.Google Scholar
  18. 18.
    B. Souček,Elektrotehnika (Zagreb) (1959) 1.Google Scholar
  19. 19.
    Z. Pučar,Croat. Chem. Acta, 28 (1956) 195.Google Scholar
  20. 20.
    Z. Pučar,Croat. Chem. Acta, 29 (1957) 1.Google Scholar

Copyright information

© Akadémiai Kiadó 1969

Authors and Affiliations

  • Ž. Proso
    • 1
  • Z. Pučar
    • 1
  1. 1.Institute “Ruder Boškovic”ZagrebYugoslavia

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