Russian Chemical Bulletin

, Volume 47, Issue 2, pp 269–272 | Cite as

The effect of self-association on the reactivity of calix[4]resorcinolarene anions with respect to esters of phosphorus acids

  • I. S. Ryzhkina
  • L. A. Kudryavtseva
  • A. R. Burilov
  • E. Kh. Kazakova
  • A. I. Konovalov
Physical Chemistry
Received:
Revised:

Abstract

The kinetics of reactions of amphiphilic anions derived from calix[4]resorcinolarenes and their aggregates withp-nitrophenyl esters of phosphorus acids were studied by spectrophotometry. The effect of hydrophobicity of the substituent R and of the composition of aqueous dimethylformamide solvent (30, 50, 80% (v/v) DMF) on these processes was investigated.

Key words

kinetics self-association micelle formation calix[4]resorcinolarenes esters of phosphorus acids 
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    H. -J. Schneider, D. Guttes, and U. Schneider,J. Am. Chem. Soc., 1988,110, 6449.CrossRefGoogle Scholar
  2. 2.
    A. R. Mustafina, R. R. Galimov, L. V. Ermolaeva, N. N. Sarvarova, A. R. Burilov, and V. S. Reznik,Izv. Akad. Nauk, Ser. Khim., 1996, 117 [Russ. Chem. Bull., 1996,45, 1111 (Engl. Transl.)].Google Scholar
  3. 3.
    H. -J. Schneider and U. Schneider, inCalixarenes, a Versatile Class of Macrocyclic Compounds, Eds. J. Vicens and V. Bohmer, Kluwer, Dordrecht, 1990, 66.Google Scholar
  4. 4.
    S. Shinkai, T. Arimura, K. Arahi, and H. Kawabata,J. Chem. Soc., Perkin Trans. 1, 1989, 2039.CrossRefGoogle Scholar
  5. 5.
    S. Arimori, T. Nagasaki, and S. Shinkai,J. Chem. Soc., Perkin Trans. 2, 1995, 679.Google Scholar
  6. 6.
    D. Gutsche, inHost-Guest Complex Chemistry Macrocycles, Ed. F. Vogtle, E. Weber, Springer-Verlag, Berlin-Heidelberg-New, York-Tokyo, 1985.Google Scholar
  7. 7.
    I. S. Ryzhkina, L. A. Kudryavtseva, E. Kh. Kazakova, A. R. Burilov, and A. I. Konovalov,Mendeleev Commun., 1997,3, 88.CrossRefGoogle Scholar
  8. 8.
    Y. Aoyama, Y. Tanaka, and S. Sugahara,J. Am. Chem. Soc., 1989,111, 5397.CrossRefGoogle Scholar
  9. 9.
    Advances in Physical Organic Chemistry, Ed. V. Gold, 8, Academic Press, London-New York, 1970.Google Scholar
  10. 10.
    J. Scheerder, R. H. Vreekamp, J. F. J. Engbergen, W. Verboom, J. P. M. van Duynhoven, and D. N. Reinhoudt,J. Org. Chem., 1996,61, 3476.CrossRefGoogle Scholar
  11. 11.
    K. N. Koh, K. Araki, A. Ikeda, H. Otsuka, and S. Shinkai,J. Am. Chem. Soc., 1996,118, 755.CrossRefGoogle Scholar
  12. 12.
    S. Shinkai, Y. Shirahama, T. Tsubaki, and O. Manabe,J. Am. Chem. Soc., 1989,111, 5477.CrossRefGoogle Scholar
  13. 13.
    S. Schinkai, Y. Shirahama, T. Tsubaki, and O. Manabe,J. Chem. Soc., Perkin Trans. 1, 1989, 1859.CrossRefGoogle Scholar
  14. 14.
    V. E. Bel'skii, F. G. Valeeva, and L. A. Kudryavtseva,Izv. Akad. Nauk, Ser. Khim., 1996, 850 [Russ. Chem. Bull., 1996,45, 805 (Engl. Transl.)].Google Scholar
  15. 15.
    S. S. Lee, Z. -H. Li, D. H. Lee, and D. H. Kim,J. Chem. Soc., Perkin Trans. 1, 1995, 2877.CrossRefGoogle Scholar
  16. 16.
    C. Reichardt,Solvents and Solvent Effects in Organic Chemistry, VCH Verlagsgesellschaft vdH, D-6940 Weinheim (FRG), 1988.Google Scholar
  17. 17.
    W. P. Jencks,Catalysis in Chemistry and Enzymology, Mc Graw-Hill Book Company, New York-St. Louis-San Francisco-London-Sidney, 1969.Google Scholar

Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • I. S. Ryzhkina
    • 1
  • L. A. Kudryavtseva
    • 1
  • A. R. Burilov
    • 1
  • E. Kh. Kazakova
    • 1
  • A. I. Konovalov
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan' Research Center of the Russian Academy of SciencesKazan'Russian Federation

Personalised recommendations