Russian Chemical Bulletin

, Volume 47, Issue 5, pp 1016–1020 | Cite as

Synthesis and spectral properties of mixedmeso-metallocenylporphyrins

  • N. M. Loim
  • N. V. Abramova
  • R. Z. Khaliullin
  • Yu. S. Lukashov
  • E. V. Vorontsov
  • V. I. Sokolov
Article

Abstract

A series of mixed porphyrins with different numbers of metallocenyl (ferrocenyl and cymantrenyl) and aryl (Ph and C6F5) groups at themeso-positions was obtained and characterized by1H NMR, electronic absorption, and mass spectra. The downfield shift of NH signals as well as the bathochromic shift ofQ-bands can be attributed to a distortion of the porphyrin macrocycle upon the introduction of bulkymeso-substituents.

Key words

porphyrins meso-metallocenylporphyrins cymantrene ferrocene dipyrrolylmethanes electronic absorption and1H NMR spectra 

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • N. M. Loim
    • 1
  • N. V. Abramova
    • 1
  • R. Z. Khaliullin
    • 1
  • Yu. S. Lukashov
    • 1
  • E. V. Vorontsov
    • 1
  • V. I. Sokolov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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