Russian Chemical Bulletin

, Volume 47, Issue 3, pp 398–401 | Cite as

Hydrogenation of acetone on technetium catalysts

  • N. N. Rimar
  • G. N. Pirogova
Physical Chemistry
Received:
Revised:

Abstract

The catalytic properties of supported mono- and bimetallic catalysts of the Tc/support, M/support, and M-Tc/support types (M=Pt, Pd, Rh, Ru, Ni, Re, Co; supports are γ-Al2O3, MgO, SiO2) were investigated in the acetone hydrogenation. The main products of this reaction are isopropyl alcohol and propane. The catalytic activity in the acetone hydrogenation of the metals studied decreases in the consequence Pt>Tc≈Rh>Pd>Ru >Ni≈Re>Co (with γ-Al2O3 as the support). The influence of support nature on the catalytic activity was investigated for the Rh−Tc system as an example. A nonadditive increase in the catalytic activity of Rh−Tc/γ-Al2O3 in comparison with monometallic catalysts was found. The state of the surface of the catalysts was characterized by the UV-VIS diffuse reflectance spectra.

Key words

acetone hydrogenation technetium bimetallic catalysts diffuse reflectance spectra 
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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • N. N. Rimar
    • 1
  • G. N. Pirogova
    • 1
  1. 1.Institute of Physical ChemistryRussian Academy of SciencesMoscowRussian Federation

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