Russian Chemical Bulletin

, Volume 46, Issue 12, pp 2147–2148 | Cite as

Catalytic transformations of oligocarbosilanes induced by AlCl3

  • N. A. Chernyavskaya
  • V. I. Aleksinskaya
  • B. G. Zavin
  • A. I. Belokon
Brief Communications
Received:

Abstract

Catalytic activation of Si−C bonds in poly(vinyltrimethylsilane) was studied using a model reaction of catalytic transformations of oligocarbosilanes Me3Si(CH2) n SiMe3 (n=2, 3) in dichlorodimethylsilane in the presence of AlCl3 as an example. The formation of ClMe2Si(CH2) n SiMe3 was established by chromato-mass spectrometry and GLC.

Key words

oligocarbosilanes functionalization catalysts polymer-analogous transformation 
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References

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • N. A. Chernyavskaya
    • 1
  • V. I. Aleksinskaya
    • 1
  • B. G. Zavin
    • 1
  • A. I. Belokon
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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