Russian Chemical Bulletin

, Volume 48, Issue 2, pp 393–394 | Cite as

Octahedral rhodium cluster [Rh6Cp6(μ6-C)]2+(PF6 -)2

  • A. R. Kudinov
  • D. V. Muratov
  • M. I. Rybinskaya
Brief Communications


The 86-electron dicationic octahedral rhodium cluster [Rh6Cp6(μ6-C)]2+(PF6 -)2 containing Cp ligands and the interstitial carbon atom was synthesized by the reaction of Rh3Cp3(μ-CO)3 with RhCp(C2H4)2

Key words

rhodium clusters octahedral clusters 


  1. 1.
    M. D. Vargas and J. N. Nicholls, inAdvances in Inorganic Chemistry and Radiochemistry, Acad. Press, 1986,30, 123.Google Scholar
  2. 2.
    J. C. Huffman, J. G. Stone, W. C. Krusell, and K. G. Caulton,J. Am. Chem. Soc., 1977,99, 5829.CrossRefGoogle Scholar
  3. 3.
    M. S. Paquette and L. F. Dah,J. Am. Chem. Soc., 1980,102, 6621.CrossRefGoogle Scholar
  4. 4.
    A. R. Kudinov, D. V. Muratov, M. I. Rybinskaya, and P. V. Petrovskii,Izv. Akad. Nauk, Ser. Khim., 1997, 579 [Russ. Chem. Bull., 199746, 559 (Engl. Transl.)].Google Scholar
  5. 5.
    R. J. Lawson and J. R. Shapley,J. Am. Chem. Soc., 1976,98, 7433.CrossRefGoogle Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • A. R. Kudinov
    • 1
  • D. V. Muratov
    • 1
  • M. I. Rybinskaya
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations