Russian Chemical Bulletin

, Volume 46, Issue 2, pp 358–361 | Cite as

Oxidation of γ-stannyl sulfides by monochloramine CB and hydrogen peroxide

  • V. I. Shcherbakov
  • N. E. Stolyarova
  • Yu. A. Kurskii
Organometallic Chemistry
Received:
  • 27 Downloads

Abstract

The first γ-trimethylstannyl sulfimide, Me3Sn(CH2)3S(=NSO2Ar)C5H11-n, was synthesized by oxidative imination of Me3Sn(CH2)3SC5H11-n with ArSO2(Na)Cl (Ar=C6H4Cl-4). Oxidation of γ-trimethylstannyl sulfimide by an alkaline solution of H2O2 gave γ-trimethylstannyl sulfoximide, Me3Sn(CH2)3S(O)(=NSO2Ar)C5H11-n, and γ-trimethylstannyl sulfone, Me3Sn(CH2)3SO2C5H11-n, the latter compound resulting from hydrolysis of the arylsulfimide group. Oxidation of stannyl sulfide by hydrogen peroxide yielded γ-trimethylstannyl sulfoxide, Me3Sn(CH2)3S(O)C5H11-n (under mild conditions) or γ-trimethylstannyl sulfone (under more severe conditions).

Key words

pentyl 3-(trimetylstannyl)propyl sulfide oxidation γ-trimethylstannyl sulfimide γ-trimethylstannyl sulfoximide γ-trimethylstannyl sulfoxide γ-trimethylstannyl sulfone 
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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • V. I. Shcherbakov
    • 1
  • N. E. Stolyarova
    • 1
  • Yu. A. Kurskii
    • 1
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii NovgorodRussian Federation

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