Chromatographia

, Volume 46, Issue 1–2, pp 40–48 | Cite as

A new gas chromatographic stationary phase: Polysiloxane with β-cyclodextrin side chain for the separation of chiral and positional isomers

  • H. B. Zhang
  • Y. Ling
  • R. N. Fu
  • Y. X. Wen
  • J. L. Gu
Originals
Received:
Revised:
Accepted:

Summary

A new stationary phase [bikis(2,6-di-O-pentyl-3-O-hex-6-enyl)-pentakis(2,6-di-O-pentyl-3-O-methyl)-β-CD-polysiloxane] was synthesized and successfully applied in GC for the separation of chiral and achiral isomers. It possesses high column efficiency and exhibits excellent separation ability for disubstituted benzenes. Some typical enantiomers and optical isomers are well separated. The separation behavior of this new phase is characterized and discussed.

Key Words

Gas chromatography Chiral stationary phase Isomers and enantiomers separation 
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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1997

Authors and Affiliations

  • H. B. Zhang
    • 1
  • Y. Ling
    • 1
  • R. N. Fu
    • 1
  • Y. X. Wen
    • 1
  • J. L. Gu
    • 1
  1. 1.Department of Chemical EngineeringBeijing Institute of TechnologyBeijingP. R. China

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