Chromatographia

, Volume 52, Issue 1–2, pp 51–57 | Cite as

Synthesis and characterization of new organometallic complexes bonded stationary phases for high-performance liquid chromatography

  • O. Bordelanne
  • M. H. Delville
  • G. Félix
  • C. Labrugère
  • A. Thienpont
  • C. Vidal
Originals Column Liquid Chromatography
Received:
Accepted:

Summary

The preparation, characterization and potential liquid chromatographic applications of various organometallic iron complexes silica stationary phases are presented. These new supports are synthesized by covalently linking ferrocene, as well as some of its cationic derivatives, to appropriately derivatized silica support matrices. These columns exhibit moderate to high selectivity towards the separation of polycyclic aromatic hydrocarbons (PAHs). A charge transfer retention mechanism has been proposed. A comparison with a reference stationary phase, 3,5-dinitrobenzamide (DNB), to quantify the acceptor power of the new stationary bonded phases, is also reported. Finally, the effect of varying the derivatives of the bonded metallocene on PAHs retention is discussed.

Key Words

Column liquid chromatography Synthesis of bonded stationary phases Organometallic complexes Charge-transfer interactions PAHs 
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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 2000

Authors and Affiliations

  • O. Bordelanne
    • 1
    • 2
  • M. H. Delville
    • 2
  • G. Félix
    • 1
  • C. Labrugère
    • 3
  • A. Thienpont
    • 1
  • C. Vidal
    • 1
  1. 1.Laboratoire d’Analyse Chimique par Reconnaissance MoléculaireEcole Nationale Supérieure de Chimie et de Physique de BordeauxTalenceFrance
  2. 2.Institut de Chimie de la Matière Condensée de Bordeaux-CNRSFrance
  3. 3.Centre de Caractérisation des Matériaux AvancésICMCB-CNRSPessacFrance

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