Reaction Kinetics and Catalysis Letters

, Volume 61, Issue 1, pp 127–132 | Cite as

Kinetics of ion-exchange of alkaline earth metals on antimony(V) phosphate cation exchanger

  • K. G. Varshney
  • Upma Gupta
  • S. M. Maheshwari
Article

Abstract

Forward and reverse ion exchange kinetics of Mg(II), Ca(II), Sr(II) and Ba(II) exchange with H(I) has been studied on antimony(V) phosphate cation exchanger applying the Nernst-Planck equations. As a result, some kinetic parameters like diffusion coefficients, activation energies, and entropies of activation have been evaluated under the conditions favoring a particle diffusion-controlled mechanism. Such kinetic parameters have also been compared with the kinetic parameters of different single and double salts.

Keywords

Kinetics ion exchange antimony(V) phosphate cation exchanger 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G.E. Boyd, A.W. Adamson, L.S. Myers:J. Am. Chem. Soc.,69, 2836 (1947).CrossRefGoogle Scholar
  2. 2.
    D. Reichenberg:J Am. Chem. Soc.,75, 589 (1953).CrossRefGoogle Scholar
  3. 3.
    R.G. Herman, A. Clearfield:J. Inorg. Nucl. Chem.,38, 853 (1976).CrossRefGoogle Scholar
  4. 4.
    W.Z. Nernst:Phys. Chem.,2, 613 (1888).Google Scholar
  5. 5.
    W.Z. Nernst:Phys. Chem.,4, 729 (1889).Google Scholar
  6. 6.
    M. Planck:Ann. Phys. Chem.,39, 161 (1890).Google Scholar
  7. 7.
    K.G. Varshney, U. Sharma, S. Anwar, A.A. Khan:Indian J. Chem. A,23, 152 (1984).Google Scholar
  8. 8.
    K.G. Varshney, S. Agrawal, K. Varshney:Coll. Surf.,13, 341 (1985).CrossRefGoogle Scholar
  9. 9.
    K.G. Varshney, A.A. Khan, S. Rani:Coll. Surf.,25, 131 (1987).CrossRefGoogle Scholar
  10. 10.
    K.G. Varshney, A.A. Khan, A.R. Khan:Bull. Chem. Soc. (Jpn.),65, 2192 (1992).CrossRefGoogle Scholar
  11. 11.
    K.G. Varshney, S.M. Maheshwari:Ecotox. Enveron. Safety,18, 1 (1989).CrossRefGoogle Scholar
  12. 12.
    K.G. Varshney, K. Varshney, S. Agrawal:Coll. Surf.,18, 67 (1986).CrossRefGoogle Scholar
  13. 13.
    F. Helfferich.Ion-exchange, Mc Graw-Hill Book Co., p. 270. New York 1962.Google Scholar
  14. 14.
    Ref.—, p. 271.Google Scholar
  15. 15.
    R.M. Barrer, R.F. Baertholomew, L.V.C. Rees:Phys. Chem. Solids,21, 12 (1961).CrossRefGoogle Scholar
  16. 16.
    K.G. Varshney, S. Rani:Indian J. Chem.,22A, 657 (1983).Google Scholar
  17. 17.
    K.G. Varshney, S. Rani:Reactive Polymers,3, 231 (1985).Google Scholar
  18. 18.
    K.G. Varshney, A.A. Khan, K. Varshney, S. Agrawal:Solv. Extr. Ion Exch.,2, 923 (1984).Google Scholar
  19. 19.
    K.G. Varshney, S. Agrawal, K. Varshney:Coll. Surf.,9, 189 (1984).CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1997

Authors and Affiliations

  • K. G. Varshney
    • 1
  • Upma Gupta
    • 1
  • S. M. Maheshwari
    • 1
  1. 1.Department of Applied Chemistry, Z.H. College of Engineering and TechnologyAligarh Muslim UniversityAligarhIndia

Personalised recommendations