Reaction Kinetics and Catalysis Letters

, Volume 67, Issue 1, pp 83–88

Catalytic oxyfunctionalization of alkanes by manganese and ruthenium clusters

  • G. L. Tembe
  • P. A. Ganeshpure


Di- and trinuclear clusters of manganese and ruthenium were used as catalysts in the oxidation of alkanes in the presence oftert-butyl hydroperoxide as oxidant. The investigations reveal marked differences in the reactivity of the manganese and ruthenium catalysts though structurally they have similar coordination environment. The probable mechanism of hydroxylation in these systems is discussed.


Manganese/ruthenium catalysts oxidation alkanes tert-butyl hydroperoxide 


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  1. 1.
    J.E. Lyons, G.W. Parshall:Catal. Today,22, 313 (1994).CrossRefGoogle Scholar
  2. 2.
    S. Menage, J.M. Vincent, C. Lambeaux, M. Fontecave:J. Mol. Catal. A: Chemical,113, 61 (1996).CrossRefGoogle Scholar
  3. 3.
    R.H. Fish, K.J. Oberhausen, S. Chen, J.F. Richardson, W. Pierce, R.M. Buchanan:Catal. Lett.,18, 357 (1993).CrossRefGoogle Scholar
  4. 4.
    R.A. Leising, J. Kim, M.A. Perez, L. Que, Jr.:J. Am. Chem. Soc.,115, 9524 (1993).CrossRefGoogle Scholar
  5. 5.
    S. Menage, J.M. Vincent, C. Lambeaux, M. Fontecave:J. Chem. Soc., Dalton Trans., 2081 (1994).Google Scholar
  6. 6.
    M. Kodera, H. Shimakoshi, K. Kano:J. Chem. Soc., Chem. Commun., 1737 (1996).Google Scholar
  7. 7.
    N. Kitajima, M. Ito, H. Fukui, Y. Moro-Oka:J. Chem. Soc., Chem. Commun., 102 (1991).Google Scholar
  8. 8.
    D. Tetard, A. Rabion, J.B. Verlhac, J. Guilhem:J. Chem. Soc., Chem. Commun., 531 (1995).Google Scholar
  9. 9.
    S. Menage, M.N. Collomb-Dumand-Sauthier, C. Lambeaux, M. Fontecave:J. Chem. Soc., Chem. Commun., 1885 (1994).Google Scholar
  10. 10.
    C.M. Che, W.T. Tang, K.Y. Wong, W.T. Wong, T.F. Lai:J. Chem. Res. (S), 30 (1991).Google Scholar
  11. 11.
    P.A. Ganeshpure, G.L. Tembe, S. Satish:Tetrahedron Lett.,36, 8861 (1995).CrossRefGoogle Scholar
  12. 12.
    G.L. Tembe, P.A. Ganeshpure, S. Satish:J. Mol. Catal. A: Chemical,121, 17 (1997).CrossRefGoogle Scholar
  13. 13.
    R.H. Fish, R.H. Fong, J.B. Vincent, G. Christou:J. Chem. Soc., Chem. Commun., 1504 (1988).Google Scholar
  14. 14.
    J.E. Sameski, D. Michos, H.H. Thorp, M. Didiuk, T. Poon, J. Blewitt, G.W. Brudvig, R.H. Crabtree:Tetrahedron Lett.,32, 1153 (1991).CrossRefGoogle Scholar
  15. 15.
    S. Menage, S.E. Vitols, P. Bergerat, E. Codjovi, O. Kahn, J.J. Girerd, M. Guillot, X. Solans, T. Calvet:Inorg. Chem.,30, 2666 (1991).CrossRefGoogle Scholar
  16. 16.
    Y. Sasaki, M. Suzuki, A. Nagasawa, A. Tokiwa, M. Ebihara, T. Yamaguchi, C. Kabuto, T. Ochi, T. Ito:Inorg. Chem.,30, 4903 (1991).CrossRefGoogle Scholar
  17. 17.
    J.A. Baumann, D.J. Salmon, S.T. Wilson, T.J. Meyer, W.E. Hatfield:Inorg. Chem.,17, 3342 (1978).CrossRefGoogle Scholar
  18. 18.
    A. Llobet, M.E. Curry, H.T. Evans, T.J. Meyer:Inorg. Chem.,28, 3131 (1989).CrossRefGoogle Scholar
  19. 19.
    P. Neubold, K. Wieghardt, B. Nuber, J. Weiss:Inorg. Chem.,28, 459 (1989)CrossRefGoogle Scholar
  20. 20.
    R.W. Mitchell, A. Spencer, G. Wilkinson:J. Chem. Soc., Dalton Trans., 846 (1973).Google Scholar
  21. 21.
    K. Srinivasan, S. Perrier, J.K. Kochi:J. Mol. Catal.,36, 297 (1986).CrossRefGoogle Scholar
  22. 22.
    R.H. Crabtree:Chem. Rev.,85, 245 (1985).CrossRefGoogle Scholar
  23. 23.
    J. Kim, E. Larka, E.C. Wilkinson, L. Que, Jr.:Angew. Chem. Int. Ed. Engl.,34 2048 (1995).CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • G. L. Tembe
    • 1
  • P. A. Ganeshpure
    • 1
  1. 1.Research CentreIndian Petrochemicals Corporation LimitedVadodaraIndia

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