Reaction Kinetics and Catalysis Letters

, Volume 63, Issue 1, pp 179–183 | Cite as

Homogeneous mono-and bimetallic catalysts for the oxidation of cyclohexene

  • Heng Jiang
  • Yun Xu
  • Shijian Liao
  • Daorong Yu
Article
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Accepted:

Abstract

In the absence of solvent, the first-row transition-metal acetylacetonate complexes and RuCl2(PPh3)3 give fairly high turnovers for the allylic oxidation of cyclohexene under atmospheric pressure of oxygen. Synergetic effect is observed for the oxidation of cyclohexene by using M(acac)n−RuCl2(PPh3)3 bimetallic catalysts.

Keywords

Allylic oxidation cyclohexene homogeneous bimetallic catalyst 
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References

  1. 1.
    E.A. Boyd, B. Costall, M.E. Kelly, P.J. Parsons:U. K. Patent, 2, 264, 299 (1993).Google Scholar
  2. 2.
    S.E. Bystrom, E.M. Larsson, B. Akermark:J. Org. Chem.,55, 5674 (1990).CrossRefGoogle Scholar
  3. 3.
    H. Alper, M. Harustiak:J. Mol. Catal.,84, 87 (1993).CrossRefGoogle Scholar
  4. 4.
    N. Mizuno, D.K. Lyon, R.G. Finke:U. S. Patent, 5,250,739 (1993).Google Scholar
  5. 5.
    M. Beller, B. Cornils, C.D. Frohning, C.W. Kohlpaintner:J. Mol. Catal.,104, 17 (1995) and the references cited therein.CrossRefGoogle Scholar
  6. 6.
    P.C. Ford, R.G. Rinker, C. Ungermann, R.M. Laine, V. Landis, S.A. Moya:J. Am. Chem. Soc.,100, 4595 (1978).CrossRefGoogle Scholar
  7. 7.
    B.D. Dombek:Organometallics,4, 1707 (1985).CrossRefGoogle Scholar
  8. 8.
    A. Fukuoda, N. Gotoh, N. Kobayashi, M. Hirano, S. Komiya:Chem. Lett., 567 (1995).Google Scholar

Copyright information

© Akadémiai Kiadó 1998

Authors and Affiliations

  • Heng Jiang
    • 1
  • Yun Xu
    • 1
  • Shijian Liao
    • 1
  • Daorong Yu
    • 1
  1. 1.Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianP. R. China

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