Chromatographia

, Volume 49, Issue 11–12, pp 643–648 | Cite as

Preparation and evaluation ofp-tert-butyl-calix[4]arene-bonded silica stationary phases for high performance liquid chromatography

  • Xiang-Zhu Xiao
  • Yu-Qi Feng
  • Shi-Lu Da
  • Yan Zhang
Originals

Summary

A new method is proposed for preparation of ap-tert-butyl-calix[4]arene-bonded silica stationary phase. The chemically modifiedp-tert-butyl-calix[4]arene is attached to silica gel via the silane coupling reagent γ-(ethylenediamino)-propyl-triethoxyl-silane. The bonded phase has been characterized by29Si and13C cross polarization/magic angle spinning solid-state nuclear magnetic spectrometry. The retention behavior of polycyclic aromatic hydrocarbons (PAHs), nucleosides and bases has been investigated on the bonded phase in the reversed-phase mode.

Key Words

Column liquid chromatography p-tert-Butyl-calix[4]arene-bonded silica Nuclear magnetic resonance spectrometry PAHs Nucleosides bases 

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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1999

Authors and Affiliations

  • Xiang-Zhu Xiao
    • 1
  • Yu-Qi Feng
    • 1
  • Shi-Lu Da
    • 1
  • Yan Zhang
    • 2
  1. 1.Department of ChemistryWuhan UniversityWuhanP.R. China
  2. 2.Laboratory of MRAMP of ChinaWuhanP.R. China

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