Summary
Raman spectra on the CuGaS2-x Se x system (x=0, 0.5, 1.0) are described for the first time. The observed structures are assigned on the basis of the analogies with binary solid solutions. The broadening of theA 1 sulphur mode seems to indicate the effect of substitutional disorder.
Riassunto
Per la prima volta si riportano gli spettri Raman del sistema CuGaS2-x Se x limitatamente alle composizionix=0, 0.5, 1. Le strutture osservate sono state attribuite in analogia con quelle dei composti binari corrispondenti. L'allargamento del modo puramente anionicoA 1, dovuto allo zolfo, sembra indicare l'effetto di un disordine sostituzionale.
Резюме
Впервые описываются Рамановские спектры системы CuGaS2-x Se x (x=0, 0.5, 1.0). Наблюденные структуры обьясняются на основе аналогий с бинарными твердыми растворами. УширениеA 1 моды серы, по-видимому, указывает на зффект разупорядочивания при замещении.
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Anedda, A., Bongiovanni, G., Raga, F. et al. Raman spectra of CuGaS2-x Se x (x=0, 0.5, 1.0). Il Nuovo Cimento D 2, 1950–1956 (1983). https://doi.org/10.1007/BF02457893
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DOI: https://doi.org/10.1007/BF02457893