Local structure of solvation of nonpolar chains in nonpolar solvents at infinite dilution
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Abstract
The SSOZ (site-site Ornstein-Zernike) equation is used to study the local structure of solvation of linear nonpolar molecules in nonpolar solvents. The atom-atomic interaction potentials are described by the Lennard-Jones potential. The chain-solvent atom-atomic pair correlation functions are calculated in relation to the chain length (number of atoms), solvent density, and the ratio of the geometrical parameters of solvent and chain atoms.
Keywords
Correlation Function Infinite Dilution Solvation Function Solute Molecule Nonpolar Solvent
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© Plenum Publishing Corporation 1996