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Ionics

, Volume 11, Issue 1–2, pp 36–45 | Cite as

Progress in the lithium insertion mechanism in Cu3P

  • B. Mauvernay
  • M. -P. Bichat
  • F. Favier
  • L. Monconduit
  • M. Morcrette
  • M. -L. Doublet
Article

Abstract

Copper phosphide, Cu3P has been synthesized using a ceramic route, and its electrochemical behaviour versus lithium has been studied studied galvanostatic and potentiodynamic measurements and in situ X-ray diffraction analysis. The insertion/extraction mechanism proceeds with the formation of at least three different LixCu3−xP (x=1, 2, 3) phases. The electrochemical behaviour of Cu3P samples obtained from ceramic and solvothermal syntheses are compared to further understanding of the complex redox mechanism occurring during insertion/extraction. First-principle electronic structure calculations show that discharge probably begins with the formation of a solid solution LixCu3−yP (x<0.5).

Keywords

Lithium Solid Solution Power Generation Renewable Energy Source Electrochemical Behaviour 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. [1]
    M.L. Doublet, F. Lemoigno, F. Gillot, L. Monconduit, Chem. Mater.14, 4126 (2002).CrossRefGoogle Scholar
  2. [2]
    L. Monconduit, F. Gillot, M.-L. Doublet; F. Lemoigno, Ionics9, 56 (2003).CrossRefGoogle Scholar
  3. [3]
    M.-P. Bichat, F. Gillot, L Monconduit, F. Favier, M. Morcrette, F. Lemoigno, M.-L. Doublet, Chem. Mater.16, 1002 (2004).CrossRefGoogle Scholar
  4. [4]
    F. Gillot, M.-P. Bichat, F. Favier, M. Morcrette, M.-L. Doublet, L. Monconduit, Electrochim. Acta47, 3137 (2004).Google Scholar
  5. [5]
    D.C.S. Souza, V. Pralong, A.J. Jacobson, L.F. Nazar, Science296, 2012 (2002).CrossRefGoogle Scholar
  6. [6]
    S. Woo, H. Sohn, Abs. 264, IMLB 12 Meeting, (2004).Google Scholar
  7. [7]
    R. Juza, K. Langer, K. von Benda, Angew. Chem. Int. Ed.7, 5 (1968).Google Scholar
  8. [8]
    L. Monconduit, M. Tillard, C. Belin, J. Solid State Chem.156, 37 (2001).CrossRefGoogle Scholar
  9. [9]
    C.S. Johnson, J.T. Vaughey, M.M. Thackeray, T. Sarakonsri, S.A. Hackney, L. Fransson, K. Edström, J.O. Thomas, Electrochem. Comm.2, 595 (2000).CrossRefGoogle Scholar
  10. [10]
    J.T. Vaughey, C.S. Johnson, A.J. Kropf, R. Benedek, M.M. Thackeray, H. Tostmann, T. Sarakonsri, S. Hackney, L. Fransson, K. Edström, J.O. Thomas, J. Power Sources97–98, 194 (2001).CrossRefGoogle Scholar
  11. [11]
    H. Pfeiffer, F. Tancret, M.-P. Bichat, L. Monconduit, F. Favier, T. Brousse, Electrochem. Comm.6, 263 (2004).CrossRefGoogle Scholar
  12. [12]
    M.P. Bichat, T. Politova, H. Pfeiffer, F. Tancret, L Monconduit, J.-L. Pascal, T. Brousse, F. Favier, J Power Sources136, 80 (2004).CrossRefGoogle Scholar
  13. [13]
    M.-P. Bichat, T. Politova, J.-L. Pascal, F. Favier, L. Monconduit, J. Electrochem. Soc.151(12), A2074-A2081 (2004).CrossRefGoogle Scholar
  14. [14]
    G. Kresse, J. Hafner, Phys. Rev. B47, 558 (1993).CrossRefGoogle Scholar
  15. [15]
    G. Kresse, D. Joubert, Phys. Rev. B59 1758 (1999).CrossRefGoogle Scholar
  16. [16]
    D. Vanderbilt, Phys. Rev. B41, 7892 (1990).CrossRefGoogle Scholar
  17. [17]
    O. Olofson, Acta Chem. Scand.26, 2777 (1972).CrossRefGoogle Scholar
  18. [18]
    M.-L. Doublet, L. Monconduit, unpublished results.Google Scholar
  19. [19]
    G. Brauer, E. Zintl, Zeit. Phys. Chem. Abt. B,37, 323–352 (1937).Google Scholar
  20. [20]
    R. Alcantara, J.L. Tirado, J.C. Jumas, L. Monconduit, J.O. Fourcade, J. Power Sources109, 308 (2002).CrossRefGoogle Scholar
  21. [21]
    V. Pralong, D.C.S. Souza, K.T. Leung, L. Nazar, Electrochem. Comm.4, 516 (2002).CrossRefGoogle Scholar
  22. [22]
    S. Grugeon, S. Laruelle, R. Herrera-Urbina, L. Dupont, P. Poizot, J.M. Tarascon, J. Electrochem. Soc.148, (4) A285-A292 (2001).CrossRefGoogle Scholar

Copyright information

© IfI - Institute for Ionics 2005

Authors and Affiliations

  • B. Mauvernay
    • 1
  • M. -P. Bichat
    • 1
  • F. Favier
    • 1
  • L. Monconduit
    • 1
  • M. Morcrette
    • 4
    • 3
  • M. -L. Doublet
    • 2
  1. 1.Laboratoire des Agrégats Moléculaires et Matériaux InorganiquesFrance
  2. 2.Laboratorie de Structure et Dynamique des Systèmes Moléculaires et SolidesFrance
  3. 3.Laboratoire de Réactivité et Chimie des SolidesUniversité Montpellier II, Place E. BataillonMontpellier Cedex 5France
  4. 4.Laboratoire de Réactivité et Chimie des SolidesUniversité de Picardie Jules Verne, 33, rue St LeuAmiens CedexFrance

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