X-ray orientation and hardness experiments on RDX explosive crystals
- 90 Downloads
- 28 Citations
Abstract
RDX (cyclotrimethylenetrinitramine) explosive crystals, typically approaching 5 mm in size, were grown by evaporation from acetone solution using production-grade crystals as starting material. Two distinctly different morphologies resulted, including one that apparently has not been previously reported in other investigations. These morphologies were characterized using Laue X-ray diffraction methods and an optical trace analysis, both involving a stereographic projection description. Microindentation experiments were performed on different prominent growth surfaces of several selected laboratorygrown crystals having the conventional morphology type. The hardness results are compared with measurements made directly on several production-grade crystals having a different morphology, and are compared with preceding measurements on a crystal having the previously unreported morphology. The latter crystal exhibited highly localized plastic deformation at the indentations as revealed by dislocation etch-pitting. Observations are made regarding the dislocation structure and cleavage properties of RDX based on its orthorhombic unit cell.
Keywords
Dislocation Structure Growth Surface Acetone Solution Localize Plastic Stereographic ProjectionPreview
Unable to display preview. Download preview PDF.
References
- 1.F. P. Bowden andA. D. Yoffe, “Fast Reactions in Solids” (Butterworths Scientific Publications, London, 1958).Google Scholar
- 2.S. J. Jacobs, T. P. Liddiard andB. E. Drimmer, in Ninth Symposium (International) on Combustion, Ithaca, New York, August 27–September 1, 1962 (Academic Press, New York and London, 1963) p. 517.Google Scholar
- 3.H. S. Napadensky, in Behavior and Utilization of Explosives in Engineering Design, Albuquerque, NM, March 1972 (New Mexico Section ASME, 1972) p. 57.Google Scholar
- 4.A. W. Campbell, M. E. Malin andT. E. Holland, in Second ONR Symposium on Detonation, Washington, DC, and White Oak, MD, February 1955 (Office of Naval Research, Department of the Navy, Washington, DC, 1955) p. 336.Google Scholar
- 5.G. K. Adams, J. Holden andE. G. Whitbread, in Extrait du Compte-rendu du XXXI Congrès International de Chimie Industrielle dans la Section Poudres et Explosifs, Liège, September 1958 [Ind. Chim. Belge Suppl. 2 (1959) 216] p. 1.Google Scholar
- 6.W. L. Elban andR. W. Armstrong, in Proceedings of the Seventh Symposium (International) on Detonation, Annapolis, MD, 16–19 June 1981 (Naval Surface Weapons Centre, Silver Spring, MD, 1982, NSWC MP 82-334) p. 976.Google Scholar
- 7.
- 8.W. C. McCrone,Anal. Chem. 22 (1950) 954.CrossRefGoogle Scholar
- 9.H. W. Fox andO. Levine, “The Wettability of RDX and PETN Crystal Surfaces”, NRL Report 4714 (1956).Google Scholar
- 10.
- 11.
- 12.
- 13.H. Klapper, in “Characterization of Crystal Growth Defects by X-Ray Methods”, edited by B. K. Tanner and D. K. Bowen (Plenum Press, New York, 1980) p. 133.Google Scholar
- 14.
- 15.J. N. Sherwood, in “The Plastically Crystalline State-Orientationally Disordered Crystals”, edited by J. N. Sherwood (Wiley and Sons, New York, 1979) p. 39.Google Scholar
- 16.T. Urbański, “Chemistry and Technology of Explosives”, Vol. III, First English Edition (Pergamon Press, Oxford, 1967) pp. 87–98.Google Scholar
- 17.J. C. Hoffsommer, D. A. Kubose andD. J. Glover, “Microanalysis of Selected Energetic Nitro Compounds by Gas/Liquid Chromatography” (GC/LC), NSWC TR 80–535 (1981).Google Scholar
- 18.K. A. Gross,J. Cryst. Growth 6 (1970) 210.CrossRefGoogle Scholar
- 19.C. S. Barrett andT. B. Massalski, “Structure of Metals” 3rd edn (McGraw-Hill, New York, 1966) pp. 211–18.Google Scholar
- 20.
- 21.P. T. Reed, in “Structures of Trinitro-Aromatic Crystals and Related Substances”, edited by P. M. Harris, AFOSR-TR-59-165 (1959) p. 6.Google Scholar
- 22.C. S. Barrett andT. B. Massalski, “Structure of Metals” 3rd edn (McGraw-Hill, New York, 1966) pp. 171–92.Google Scholar
- 23.J. Bleay, R. M. Hooper, R. S. Narang andJ. N. Sherwood.J. Cryst. Growth 43 (1978) 589.CrossRefGoogle Scholar
- 24.J. N. Sherwood, Private communication (1982).Google Scholar
- 25.R. W. Armstrong andC. Cm. Wu, in “Microstructural Analysis: Tools and Techniques”, edited by J. L. McCall and W. M. Mueller (Plenum Press, New York and London, 1973) p. 169.Google Scholar
- 26.R. W. Armstrong, in “Characterization of Crystal Growth Defects by X-Ray Methods”, edited by B. K. Tanner and D. K. Bowen (Plenum Press, New York and London, 1980) p. 349.Google Scholar
- 27.R. C. Bowers, J. B. Romans andW. A. Zisman, “Mechanisms Involved in the Impact Sensitivity of RDX Explosive Compositions”, NRL Report 5463 (1960).Google Scholar
- 28.C. E. Morris, in Sixth Symposium (International) on Detonation, Coronado, CA, August 1976 (Office of Naval Research, Department of the Navy, Arlington, VA, ACR-221) p. 396.Google Scholar