Hyperfine Interactions

, Volume 41, Issue 1, pp 669–672 | Cite as

A CEMS-study of the passive layer on iron and steel

  • W. Meisel
  • U. Stumm
  • C. Thilmann
  • R. Gancedo
  • P. Gütlich
Surface Phenomena Catalysis

Abstract

From AES, ICEMS, and DCEMS experiments it was concluded that the passive layer formed on steel in a phosphate buffer consists of γ-FeOOH. Its thickness increases from 0.5 to 3.5 nm throughout the passive region. It is covered by noncorrelated layers of a precipitate and an adsorbate.

Keywords

Iron Phosphate Thin Film Phosphate Buffer Passive Layer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

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    N. Sato, G. Okamoto in Comprehensive treatise of electrochemistry, ed. J.O'M.Bockris (Plenum Press, New York 1981)Google Scholar
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    F. Salvat, J. Parellada, Nucl. Instr. Meth. B1 (1984) 70CrossRefADSGoogle Scholar
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    D. Liljequist et al., Phys. Rev. B31 (1985) 4131CrossRefADSGoogle Scholar

Copyright information

© J.C. Baltzer A.G., Scientific Publishing Company 1988

Authors and Affiliations

  • W. Meisel
    • 1
  • U. Stumm
    • 1
  • C. Thilmann
    • 1
  • R. Gancedo
    • 1
  • P. Gütlich
    • 1
  1. 1.Institut für Anorganische und Analytische ChemieJohannes Gutenberg-UniversitätMainzW.-Germany

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