Ionics

, Volume 4, Issue 5–6, pp 347–354 | Cite as

Hydrogen in perovskites: Mechanism of solubility, chemical state, effect on electron subsystem, phase transformation

  • Yu. M. Baikov
  • W. Gunther
  • V. P. Gorelov
  • P. Colomban
  • R. Baddour-Hadjean
Article
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Accepted:

Abstract

The phenomena of hydrogen/water solubility in YBa2Cu3O7-δ and BaCeO3 undoped and doped by Y and Nd are considered. New experimental data as well as recently published data have been accumulated to discuss the chemical state of protons, taking into account the fairly strong interaction of the protons with the electron subsystem. Phase transformation of the studied oxides induced by hydrogen/water intercalation were revealed by the investigations of thermal effects, X-ray diffraction, Raman spectroscopy, inelastic neutron scattering and nuclear quadrupole resonance.

Keywords

Oxide Hydrogen Spectroscopy Experimental Data Analytical Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© IfI - Institute for Ionics 1996

Authors and Affiliations

  • Yu. M. Baikov
    • 1
  • W. Gunther
    • 2
  • V. P. Gorelov
    • 3
  • P. Colomban
    • 4
  • R. Baddour-Hadjean
    • 4
  1. 1.Ioffe Physical Technical InstituteSt-PetersburgRussia
  2. 2.Fritz-Haber-Institut der MPG, Anorganische ChemieD-BerlinGermany
  3. 3.Institute of High-Temperature ElectrochemistryUral Divison of the Russian Academy of ScienceEkaterinburgRussia
  4. 4.LADIR-CNRSTiaisFrance

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