Ionics

, Volume 5, Issue 3–4, pp 232–235 | Cite as

Characterisation of plasticized PMMA based solid polymer electrolytes

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Abstract

Polymer electrolyte films prepared from poly (methyl methacrylate) and LiAsF6 with different concentrations of plasticizer (DBP) are described. The formation of polymer-salt complexes has been confirmed by XRD and FTIR spectral studies. The temperature dependence of the conductivity of the polymer films obeys the VTF relation. Values of conductivities of the polymer complexes are presented and discussed.

Keywords

Polymer Methyl Physical Chemistry Analytical Chemistry Electronic Material 
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5. References

  1. [1]
    F. Croce, F. Gerace, G. Dautzenberg, S. Passerini, G.B. Appetecchi and B. Scrosati, Electrochim. Acta39, 2187 (1994).CrossRefGoogle Scholar
  2. [2]
    K.M. Abraham, in: Applications of Electroactive Polymers (B. Scrosati, Ed.) Chapman and Hall London, 1993) p. 75.Google Scholar
  3. [3]
    T. Iijima, Y. Tyoguchi, and N. Eda, Denki Kagaku53, 619 (1985).Google Scholar
  4. [4]
    O. Bohnke, G. Frand, M. Rezrazi, C. Rousselot, and C. Truche, Solid State Ionics66, 97 (1993).Google Scholar
  5. [5]
    W. Wixwat, J.R. Stevens, A.M. Anderson, and C.G. Cranqvist, in: Second International Symposium on Polymer Electrolytes (B. Scrosati, Ed.) Elsevier, Appl. Sci. Pub., London, 1990, p. 461.Google Scholar
  6. [6]
    G.B. Appetecchi, F. Croce, and B. Scrosati, Electrochimica Acta40, 991 (1995).CrossRefGoogle Scholar
  7. [7]
    S.S. Sekhon, Pradeep and S.A. Agnihotry, Solid State Ionics 217 (1998).Google Scholar
  8. [8]
    D.L. Vien, N.B. Colthup, W.G. Fateley, J.G. Grasselli, Infrared and Raman Characteristic Frequencies of Organic Molecules, Academic Press, Inc. New York, 1991, p. 85.Google Scholar
  9. [9]
    O. Bohnke, G. Frand, M. Rezrazi, C. Rousselot, and C. Truche, Solid State Ionics66, 105 (1993).Google Scholar
  10. [10]
    M.B. Armand, J.M. Chabagno, and M.J. Duclot, in: Fast-ion Transport in Solids, (P. Vasgishta, J.N. Mundy and G. Shenoy, Eds.) North-Holland Amsterdam, 1979, p. 131.Google Scholar
  11. [11]
    H. Vogel, Phys. Z.22, 645 (1922).Google Scholar
  12. [12]
    V.G. Tamman and H.Z. Hesse, Anorg. Allg. Chem.19, 245 (1926).Google Scholar
  13. [13]
    G.S. Fulcher, J. Am. Ceram. Soc.8, 339 (1925).Google Scholar

Copyright information

© IfI - Institute for Ionics 1999

Authors and Affiliations

  1. 1.Department of PhysicsAlagappa UniversityKaraikudiIndia

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