Hyperfine Interactions

, Volume 47, Issue 1–4, pp 179–202

Edge spectroscopy

  • G. Wortmann
Oral Contributions

Abstract

The near-edge X-ray absorption fine structure can provide information on the chemical form and local structure as well as on the electronic and even magnetic properties of the investigated systems on a microscopic (atomic) scale. Selected examples of the application of edge spectroscopy are presented with emphasis on the valence determination in rare-earth systems, where similar information can be obtained by Mössbauer spectroscopy.

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References

  1. [1]
    Synchrotron Radiation Research ed. H. Winick and S. Doniach (Plenum Press, New York, 1980) Ch. 10,12 and 13.Google Scholar
  2. [2]
    Handbook on Synchrotron Radiation, ed. E.E. Koch (North-Holland, Amsterdam, 1983).Google Scholar
  3. [3]
    X-Ray Absorption, ed. D.C. Koningsberger and R. Prins (Wiley, New York, 1988).Google Scholar
  4. [4]
    EXAFS and Near Edge Structure III, ed. K.O. Hodgson, B. Hedman and J.E. Penner-Hahn (Springer Proceedings in Physics 2, Berlin, 1984).Google Scholar
  5. [5]
    EXAFS and Near Edge Structure IV, ed. P. Lagarde, D. Raoux and J. Petiau, J. de Phys. 47, Colloq. C8, Suppl. 12 (1986).Google Scholar
  6. [6]
    Proc. of the XAFS-V Conf. (Seattle, 1988), to appear in Physica B.Google Scholar
  7. [7]
    For a recent review of edge spectroscopy on rare-earth systems, see J. Röhler, in:Handbook on the Physics and Chemistry of Rare Earths, Vol. 10, ed. K.A. Gschneidner, Jr., L. Eyring and S. Hüfner (Elsevier, Amsterdam, 1987) p. 453.Google Scholar
  8. [8]
    D. Norman, J. Phys. C19(1986)3273.ADSGoogle Scholar
  9. [9]
    G. Schütz, W. Wagner, W. Wilhelm, P. Kienle, R. Zeller, R. Frahm and G. Materlik, Phys. Rev. Lett. 548(1987)737.ADSGoogle Scholar
  10. [10]
    K.H. Frank, Ph.D. Thesis, Freie UniversitÄt Berlin (1984).Google Scholar
  11. [11]
    See, for example, C.R. Natoli and M. Benfatto, in ref. [5], p. C8-11; M. Benfatto et al., ibid. p. C8-25.Google Scholar
  12. [12]
    I. Nowik, Hyp. Int. 13(1983)89.CrossRefGoogle Scholar
  13. [13]
    E.R. Bauminger, G.M. Kalvius and I. Nowik, in:Mössbauer Isomer Shifts, ed. G.K. Shenoy and F.E. Wagner (North-Holland, Amsterdam, 1978) p. 661.Google Scholar
  14. [14]
    J. Feldhaus, Ph.D. Thesis, Freie UniversitÄt Berlin (1982).Google Scholar
  15. [15]
    G. Materlik, B. Sonntag and M. Tausch, Phys. Rev. Lett. 51(1983)267.CrossRefGoogle Scholar
  16. [15a]
    G. Materlik, J.E. Müller and J.W. Wilkins, Phys. Rev. Lett. 50(1983)267.CrossRefADSGoogle Scholar
  17. [16]
    Valence Instabilities, ed. P. Wachter and J. Boppart (North-Holland, Amsterdam, 1982).Google Scholar
  18. [17]
    Proc. Int. Conf. on Valence Fluctuations, J. Magn. Magn. Mater. 47 & 48(1985).Google Scholar
  19. [18]
    E.R. Bauminger, D. Froindlich, I. Nowik, S. Ofer, I. Felner and I. Mayer, Phys. Rev. Lett. 30(1973)1053.CrossRefADSGoogle Scholar
  20. [19]
    J. Röhler, D. Wohlleben, G. Kaindl and H. Balster, Phys. Rev. Lett. 49(1982)65.CrossRefADSGoogle Scholar
  21. [20]
    E.V. Sampathkumaran, L.C. Gupta, R. Vijayaraghavan, K.V. Gopalakrishnan, R.G. Pillay and H.G. Devare, J. Phys. C14(1981)L237.ADSGoogle Scholar
  22. [21]
    B. Perscheid, I. Nowik, G. Wortmann, G. Schmiester, G. Kaindl and I. Felner, Z. Phys. B 73(1989)511.CrossRefGoogle Scholar
  23. [22]
    D. Wohlleben, in:Valence Fluctuations in Solids, ed. L.M. Falicov, W. Hanke and M.P. Maple (North-Holland, Amsterdam, 1981) p. 1.Google Scholar
  24. [23]
    M. Martin, J.B. Boyce, J.W. Allen and F. Holtzberg, Phys. Rev. Lett. 44(1980)1275.CrossRefADSGoogle Scholar
  25. [24]
    H. Launois, M. Rawiso, E. Holland-Moritz, R. Pott and D. Wohlleben, Phys. Rev. Lett. 44(1980)1271.ADSGoogle Scholar
  26. [25]
    K. Syassen, G. Wortmann, J. Feldhaus, K.H. Frank and G. Kaindl, Phys. Rev. B26(1982) 4775.ADSGoogle Scholar
  27. [26]
    K.H. Frank, G. Kaindl, J. Feldhaus, G. Wortmann, W. Krone, G. Materlik and H. Bach, in ref. [16],. p. 189.Google Scholar
  28. [27]
    K.H. Frank et al., to be published.Google Scholar
  29. [28]
    G. Wortmann, K.H. Frank, E.V. Sampathkumaran, B. Perscheid, G. Schmiester and G. Kaindl, J. Magn. Magn. Mater. 49(1985)325.CrossRefADSGoogle Scholar
  30. [29]
    E. Kemly, M. Croft, V. Murgai, L.C. Gupta, C. Godart, R.D. Parks and C.U. Segre, J. Magn. Magn. Mater. 47 & 48(1985).Google Scholar
  31. [30]
    J. Röhler, J. Magn. Magn. Mater. 47 & 48(1985)175.CrossRefADSGoogle Scholar
  32. [31]
    G. Wortmann, W. Krone and B. Perscheid, J. de Phys. 47(1986)C8–979.Google Scholar
  33. [32]
    C.U. Segre, M. Croft, J.A. Hodges, V. Murgai, L.C. Gupta and R.D. Parks, Phys. Rev. Lett. 49(1982)1947.CrossRefADSGoogle Scholar
  34. [33]
    M.M. Abd-Elmeguid, Ch. Sauer, K. Köbler and W. Zinn, Z. Phys. B60(1983)239.Google Scholar
  35. [34]
    M.M. Abd-Elmeguid, Ch. Sauer and W. Zinn, Phys. Rev. Lett. 55(1985)2467.CrossRefADSGoogle Scholar
  36. [35]
    G. Wortmann, B. Perscheid, I. Nowik, G. Kaindl and I. Felner, to be published.Google Scholar
  37. [36]
    E. Bauminger, I. Felner, D. Levron, I. Nowik and S. Ofer, Phys. Rev. Lett. 33(1974)890.CrossRefADSGoogle Scholar
  38. [36a]
    E. Bauminger et al., J. de Phys. C6(1979)61.Google Scholar
  39. [37]
    I. Felner and I. Nowik, J. Phys. Chem. Solids 39(1978)767.Google Scholar
  40. [38]
    G. Wortmann, W. Krone, E.V. Sampathkumaran and G. Kaindl, Hyp. Int. 28(1986)581.Google Scholar
  41. [39]
    G. Wortmann, unpublished results.Google Scholar
  42. [40]
    E.V. Sampathkumaran, G. Kaindl, W. Krone, B. Perscheid and R. Vijayaraghavan, Phys. Rev. Lett. 54(1985)1067.CrossRefADSGoogle Scholar
  43. [41]
    E.V. Sampathkumaran, B. Perscheid, W. Krone and G. Kaindl, J. Magn. Magn. Mater. 47 &48(1985)410.ADSGoogle Scholar
  44. [42]
    E.V. Sampathkumaran, B. Perscheid and G. Kaindl, Solid State Commun. 51(1984)701.CrossRefGoogle Scholar
  45. [43]
    G.K. Wertheim, E.V. Sampathkumaran, C. Laubschat and G. Kaindl, Phys. Rev. B (Rapid Commun.) 31(1985)6836.ADSGoogle Scholar
  46. [44]
    H. Boppart and P. Wachter, Phys. Rev. Lett. 53(1984)1759.CrossRefADSGoogle Scholar
  47. [44a]
    H. Boppart, W. Rehwald, E. Kaldis and P. Wachter, in ref. [16],. p. 81.Google Scholar
  48. [45]
    J. Röhler, E. Dartyge, A. Fontaine, A. Jucha, K. Keulerz and D. Sayers, in ref. [4], p. 385.Google Scholar
  49. [46]
    J. Moser, G.M. Kalvius and W. Zinn, Hyp. Int. 41(1988)499.Google Scholar
  50. [47]
    M. Pasternak and R.D. Taylor, Hyp. Int. (1989), this volume.Google Scholar
  51. [48]
    H.G. Zimmer, K. Takemura, K. Fischer and K. Syassen, Phys. Rev. B29(1984)2350.ADSGoogle Scholar
  52. [49]
    J. Röhler, Physica B144(1986)27.Google Scholar
  53. [50]
    J.N. Farell and R.D. Taylor, Phys. Rev. Lett. 58(1987)2478.ADSGoogle Scholar
  54. [50a]
    R.D. Taylor and J.N. Farell, J. App. Phys. 61(1987)3669.ADSGoogle Scholar
  55. [51]
    C.M. Varma, Rev. Mod. Phys. 48(1976)219.CrossRefADSGoogle Scholar
  56. [52]
    I. Felner, I. Nowik, D. Vaknin, U. Potzel, J. Moser, G.M. Kalvius, G. Wortmann, G. Schmiester, G. Hilscher, E. Gratz, C. Schmitzer, N. Pillmayer, K.G. Prasad, H. de Waard and H. Pinto, Phys. Rev. B35(1987)6956.ADSGoogle Scholar
  57. [53]
    See refs. [7], [16], [17].Google Scholar
  58. [54]
    E.V. Sampathkumaran, Hyp. Int. 28(1986)183.Google Scholar
  59. [55]
    G. Kaindl, G.K. Wertheim, G. Schmiester and E.V. Sampathkumaran, Phys. Rev. Lett. 58(1987)606.CrossRefADSGoogle Scholar
  60. [55a]
    G. Kaindl and G.K. Wertheim, Phys. Rev. Lett. 61(1988)2629.CrossRefADSGoogle Scholar
  61. [56]
    G. Kaindl, G. Schmiester, E.V. Sampathkumaran and P. Wachter, Phys. Rev. B38(1988) 10174.ADSGoogle Scholar
  62. [57]
    G. Kalkowski, G. Kaindl, G. Wortmann, D. Lentz and S. Krause, Phys. Rev. B37(1988)1376.ADSGoogle Scholar
  63. [58]
    A. Kotani, T. Jo and J.C. Parlebas, Adv. Phys. 37(1988)37.CrossRefADSGoogle Scholar
  64. [59]
    G. Kaindl, G. Kalkowski, W.D. Brewer, E.V. Sampathkumaran, F. Holtzberg and A. Schach von Wittenau, J. Magn. Magn. Mater. 47 & 48(1985)181.CrossRefADSGoogle Scholar
  65. [60]
    D. Gignoux, F. Givord and J. Voivon, J. Less-Common Metals 94(1983)165.Google Scholar
  66. [60a]
    D. Gignoux and J. Voivon, Phys. Rev. B32(1985)4822.ADSGoogle Scholar
  67. [61]
    T. Schedel, Diplom Thesis, Freie UniversitÄt Berlin (1987);Google Scholar
  68. [61a]
    T. Schedel and G. Wortmann, HAYSLAB Annual Report 1987, p. 356;Google Scholar
  69. [61b]
    T. Schedel et al., to be published.Google Scholar
  70. [62]
    A. Bianconi, M. de Santis, A. DiCicco, A.M. Flank, A. Fontaine, P. Lagarde, H. Katayama-Yoshida, A. Kotani and A. Marcelli, Phys. Rev. B38(1988)7196.ADSGoogle Scholar
  71. [63]
    G. Kaindl, O. Strebel, A. Kolodziejczyk, W. SchÄfer, R. Kiemel, S. Lösch, S. Kemmler-Sack, R. Hoppe, H.P. Müller and D. Kissel, in ref. [6], and to be published.Google Scholar
  72. [64]
    B. Lengeler, M. Wilhelm, B. Jobst, W. Schwaen, B. Seebader and U. Hillebrecht, Solid State Commun. 65(1988)1545.CrossRefGoogle Scholar
  73. [65]
    See, for example, various contributions in ref. [6] and K.B. Garg et al., Phys. Rev. B38 (1988)244.ADSMathSciNetGoogle Scholar
  74. [66]
    J. Stöhr, inref. [3].Google Scholar
  75. [67]
    F. Sette, J. Stöhr and A.P. Hitchcook, J. Chem. Phys. 110(1984)577.Google Scholar
  76. [68]
    J. Stöhr, F. Sette and A.L. Johnson, Phys. Rev. Lett. 53(1984)1684.ADSGoogle Scholar
  77. [69]
    G. Wortmann, W. Krone, V. Biebesheimer, G. Kaindl and S. Roth, Springer Tracts in Solid-State Science 63(1985)41.Google Scholar
  78. [70]
    W. Krone, G. Wortmann and G. Kaindl, Synthetic Metals, in print;Google Scholar
  79. [70a]
    G. Wortmann et al., Synthetic Metals 23(1988)139.CrossRefGoogle Scholar
  80. [71]
    G. Wortmann, W. Krone and G. Kaindl, in ref. [6].Google Scholar
  81. [72]
    M. Tiedtke and G. Wortmann, Contribution to this conference.Google Scholar
  82. [73]
    G. Schütz, M. Knülle, R. Wienke, W. Wilhelm, W. Wagner, P. Kienle and R. Frahm, Z. Phys. B73(1988)67.Google Scholar
  83. [74]
    G. Schütz et al., in ref. [6] and HASYLAB Annual Report 1988, p. 201.Google Scholar

Copyright information

© J.C. Baltzer AG, Scientific Publishing Company 1989

Authors and Affiliations

  • G. Wortmann
    • 1
  1. 1.Institut für Atom- und FestkörperphysikFreie UniversitÄt BerlinBerlin 33Germany

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