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Chromatographia

, Volume 20, Issue 8, pp 466–470 | Cite as

Gas chromatographic analysis of the thermal and photochemical reaction products in diethyl ether solutions of nitrogen oxides

  • J. Szychlinski
  • E. Oleksy
  • K. Windorpska
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  • 27 Downloads

Summary

When dissolved in diethyl ether, nitrogen dioxide reacts with the solvent, slowly at room temperature, more rapidly on heating of UV irradiation. A complex mixture of products is formed in which further changes are observed after prolonged storge: these are less pronounced if the unreacted nitrogen oxides are removed. A gas chromatographic method was applied for the identification of the majority of products. Irradiation does not change significantly the qualitative and quantitative composition of the reaction products. The reaction is thus the so-called photo-induced process [ΔG<0]. Preliminary suggestions are made concerning the reaction mechanism.

Key Words

Gas chromatography Nitrogen dioxide Diethyl ether Photo-induced reaction 

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References

  1. [1]
    D. K. Hsu, D. L. Monts, R. N. Zere, Spectral Atlas of Nitrogen Dioxide, Academic, Press, New York 1978.Google Scholar
  2. [2]
    L. C. Lee, C. C. Chiang, J. Chem. Phys.76, 4462 (1982).Google Scholar
  3. [3]
    K. Shibuya, F. Stuhl, J. Chem. Phys.76, 1184 (1982).CrossRefGoogle Scholar
  4. [4]
    H. G. Weber, F. Bylicki, F. König, H. Burkhard, J. Wieland, Z. Phys.A309, 363 (1983).Google Scholar
  5. [5]
    K. Shibuya, T. Imajo, K. Obi, I. Tanaka, J. Phys. Chem.88, 1457 (1984).CrossRefGoogle Scholar
  6. [6]
    R. S. Tapper, R. I. Whetten, G. S. Ezra, E. R. Grant, J. Phys. Chem.88, 1273 (1984).CrossRefGoogle Scholar
  7. [7]
    C. B. McKendrick, C. Fotakis, R. J. Donovan, J. Photochem.20, 175 (1982).CrossRefGoogle Scholar
  8. [8]
    B. H. Rockney, G. E. Hall, E. R. Grant, J. Chem. Phys.78, 7124 (1983).CrossRefGoogle Scholar
  9. [9]
    M. Kawasaki, K. Kasatani, H. Sato, H. Shinohara, N. Nishi, Chem. Phys.78, 65 (1983).CrossRefGoogle Scholar
  10. [10]
    T. G. Slanger, M. J. Dyer, W. K. Bischel, Bull. Soc. Chim. Belges,92, 637 (1983).Google Scholar
  11. [11]
    F. Lahmani, C. Lardeux, D. Solgadi, J. Chim. Phys.80, 705 (1983).Google Scholar
  12. [12]
    L. Bigio, R. S. Tapper, E. R. Grant, J. Phys. Chem.88, 1271 (1984).CrossRefGoogle Scholar
  13. [13]
    W. P. Bulatov, M. A. Yoffe, M. Z. Kozliner, Chem. Phys. (USSR)3, 988 (1984).Google Scholar
  14. [14]
    G. R. Long, L. D. Prentice, S. E. Bialkowski, Appl. Phys.B34, 97 (1984).CrossRefGoogle Scholar
  15. [15]
    A. M. Renlund, W. Trott, Chem. Phys. Lett.107, 555 (1984).CrossRefGoogle Scholar
  16. [16]
    R. R. Dickerson, D. H. Stedman, A. C. Delany, J. Geophys. Res.C87, 4933 (1982).Google Scholar
  17. [17]
    R. A. Cox, J. Photochem.25, 173 (1984).CrossRefGoogle Scholar
  18. [18]
    T. Shimazaki, J. Atmos. and Terr. Phys.46, 173 (1984).Google Scholar
  19. [19]
    D. C. Zafiriou, M. McFarland, GRJ Geophys. Res.86C, 3173 (1980).Google Scholar
  20. [20]
    T. E. Graedel, Bull. N. Y. Acad. Med.56, 881 (1980).Google Scholar
  21. [21]
    D. J. Kewely, Atmos. Environ,14, 1445 (1980).Google Scholar
  22. [22]
    B. C. Morrison, Jr., J. Heicklen, J. Photochem.15, 131 (1981).CrossRefGoogle Scholar
  23. [23]
    R. Y. Wade, M. J. Wong, E. Y. Leone, L. H. Robinson, R. E. DeMandel, Gov. Rep. Announce Index (U.S.)81, 439 (1981).Google Scholar
  24. [24]
    T. Ibusuki, J. Japan Soc. Air Pollut.19, 141 (1984).Google Scholar
  25. [25]
    L. G. Britton, A. G. Clarke, Atmos. Environ.14, 829 (1980).Google Scholar
  26. [26]
    C. A. Bignozzi, C. Chiorboli, A. Maldotti, V. Carassiti, Ann. Chim. (Rome)70, 453 (1980).Google Scholar
  27. [27]
    R. J. Countess, G. T. Wolff, R. M. Whitbeck, J. Environ. Sci. Health A16, 1 (1981).Google Scholar
  28. [28]
    B. Veyret, J. C. Rayez, R. Lesclaux, J. Phys. Chem.86, 3424 (1982).CrossRefGoogle Scholar
  29. [29]
    H. Takagi, N. Washida, H. Akimoto, M. Okuda, Spectr. Lett.15, 145 (1982).Google Scholar
  30. [30]
    C. Fairbridge, R. A. Ross, Canad. J. Chem.60, 893 (1982).Google Scholar
  31. [31]
    F. Sakamaki, F. Okuda, H. Akimoto, H. Yamazaki, Environ Sci. Technol.16, 45 (1982).Google Scholar
  32. [32]
    S. Yanagihara, I. Shimada, E. Shinoyama, F. Chisaka, K. Saito, T. Ishii, Techn. Rept. Mech. Eng. Lab.1976 (86) 70.Google Scholar
  33. [33]
    M. Jarosiewicz, J. Dzychlinski, Roczniki Chem.48, 1545 (1974).Google Scholar
  34. [34]
    M. Jarosiewicz, J. Dzychlinski, J. Photochem. in press.Google Scholar
  35. [35]
    J. Supniewski, Preparatyka Nieorg., Warsaw (Poland), PWN, 1958, p. 264.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • J. Szychlinski
    • 1
  • E. Oleksy
    • 1
  • K. Windorpska
    • 1
  1. 1.Institute of ChemistryUniversity of GdańskGdańskPoland

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