Chromatographia

, Volume 15, Issue 10, pp 667–668 | Cite as

Effect of the alkyl chain length of the bonded stationary phase on solute retention in reversed-phase high-performance liquid chromatography

  • K. Jinno
Short Communications
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Accepted:

Summary

A comparison of the chromatographic retention characteristics of nonpolar bonded stationary phases was investigated. The results show that the interactions between the solutes and the stationary phases having C2, C8 and C18 alkyl groups are almost similar in the range of the mobile phase investigated. This interaction is considered as the solvophobic effect.

Key Words

HPLC Reversed-phase Effect of chain length of Stationary phase Bonded phases 
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References

  1. [1]
    H. Hemetsberger, W. Maasfeld, H. Ricken, Chromatographia9, 303 (1976).CrossRefGoogle Scholar
  2. [2]
    J. H. Knox, A. Pryde, J. Chromatogr.112, 171 (1975).CrossRefGoogle Scholar
  3. [3]
    C. H. Lochmüller, D. R. Wilder, J. Chromatogr. Sci.17, 574 (1979).Google Scholar
  4. [4]
    R. E. Majors, M. J. Hopper, J. Chromatogr. Sci.12, 767 (1974).Google Scholar
  5. [5]
    R. K. Gilpin, J. A. Korpi, G. A. Janicki, Anal. Chem.47, 1498 (1975).CrossRefGoogle Scholar
  6. [6]
    K. Karch, I. Sebestian, I. Halász, J. Chromatogr.122, 3 (1976).CrossRefGoogle Scholar
  7. [7]
    K. K. Unger, N. Becker, P. Roumeliotis, J. Chromatogr.125, 115 (1976).CrossRefGoogle Scholar
  8. [8]
    E. J. Kikta, Jr., E. Grushka, Anal. Chem.48, 1098 (1976).CrossRefGoogle Scholar
  9. [9]
    H. Hemetsberger, M. Kellerman, H. Ricken, Chromatographia10, 726 (1977).CrossRefGoogle Scholar
  10. [10]
    P. Roumeliotis, K. K. Unger, J. Chromatogr.149, 211 (1978).CrossRefGoogle Scholar
  11. [11]
    G. E. Berendsen, L. de Galan, J. Liquid Chromatogr.1, 561 (1978).Google Scholar
  12. [12]
    M. C. Hennion, C. Picard, M. Cande, J. Chromatogr.166, 21 (1978).CrossRefGoogle Scholar
  13. [13]
    N. Tanaka, K. Sakaguchi, M. Araki, J. Chromatogr.199, 327 (1980).CrossRefGoogle Scholar
  14. [14]
    C. H. Lochmüller, H. H. Hangac, D. R. Wilder, J. Chromatogr. Sci.19, 130 (1981).Google Scholar
  15. [15]
    N. Tanaka, Y. Tokuda, K. Iwaguchi, M. Araki, in: “Advances in Chromatography 1982”,A. Zlatkis (ed.), University of Houston, 1982, pp. 267–278.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1982

Authors and Affiliations

  • K. Jinno
    • 1
  1. 1.School of Materials ScienceToyohashi University of TechnologyToyohashiJapan

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