Chromatographia

, Volume 27, Issue 11–12, pp 544–548 | Cite as

Gas-chromatographic study of the thermodynamic properties of systems containing linear alkenes and alkynes

  • K. Kuningas
  • S. Rang
  • T. Kailas
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Summary

The selectivity of silicone phases OV-101, OV-17 and OV-225 with respect to the retention indices and thermodynamic functions of solution (relative molar enthalpies, entropies and free energies) of n-alkene and n-alkyne isomers and homologs was investigated and correlated with the molecular structure of the isomers.

Key Words

Gas-liquid chromatography Thermodynamic parameters n-Alkenes n-Alkynes Silicone phases 
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References

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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1989

Authors and Affiliations

  • K. Kuningas
    • 1
  • S. Rang
    • 1
  • T. Kailas
    • 1
  1. 1.Institute of ChemistryEstonian Academy of SciencesTallinnEstonian SSR

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