Two different gas chromatographic methods are used for the determination of hydrocarbon type distribution in naphtha and gasoline samples with final boiling points up to 275 °C. The methods are based either on a single capillary column or on a valve-switched packed column system. Both methods give extensive information on paraffins, olefins, naphthenes and aromatics in total as well as by carbon-number. In each case the analysis is fully automated with a computer controlling the entire analysis from injection to results presentation. The advantages and limitations of both methods are discussed.
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ASTM Standard D1319, Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption, (1973).
J. C. Suatoni, R. W. Swab, J. Chromatogr. Sci.13, 367 (1975).
D. R. Baker, Hydrocarbon Group Type Analysis of Gasoline by High Performance Liquid Chromatography, Hewlett-Packard Application Note AN 232-9 (1978).
H. Boer, P. van Arkel, W. J. Boersma, Chromatographia13, 500 (1980).
L. Huber, J. de Jong. H. Spaans, Hydrocarbon Type Analyser for Naphthas and Gasolines, Hewlett-Packard Application Note AN 228-24 (1982).
H. H. Nigs, P. A. Jacobs, J. of Chromatogr. Sci.19, 40 (1981).
M. G. Block, R. B. Callen, J. H. Stockinger, J. Chromatogr. Sci.15, 504 (1977).
J. V. Brunnok, L. A. Luke, Anal. Chem.40, 2158 (1968).
T. J. Stark, P. Larson, Separation of C1–C5 Hydrocarbons on Crosslinked Methyl Siloxane Fused Silica WCOT Columns. To be published in J. Chromatogr. Sci., July 1982.
L. Huber, Determination of the Calorific Value of Natural Gases by Gas Chromatography (in German). To be published in gwf-gas/erdgas, September 1982.
L. Huber, Gas Chromatographic Analysis of Hydrocarbons up to C20 and Inert Gases in Natural Gas and Condensates by Using a Combination of Packed and Capillary Columns, unpublished.
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Huber, L. Hydrocarbon type analysis by gas chromatograph using a single capillary column and a multi-column valve system. Chromatographia 16, 282–285 (1982). https://doi.org/10.1007/BF02258920
- Gas chromatography
- Naphtha analysis
- Gasoline analysis
- Hydrocarbon type analysis