, Volume 16, Issue 1, pp 166–168 | Cite as

Contribution of adsorption to retention data in glass capillary gas chromatography part. I. Polar stationary phases

  • J. Krupčik
  • E. Matisová
  • J. Garaj
  • L. Soják
  • V. G. Brezkin
Short Communications


The influence of the film thickness of Carbowax 20M coated onto glass surfaces (series of columns with different mode of surface treatment) upon the retention indices of solutes which exhibit tendency to hydrogen bonding has been investigated. Limiting values of Kovats indices, I, are calculated for all the columns examined.

Key Words

Glass capillary columns Retention data Adsorption Influence of stationary phase film thickness 


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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1982

Authors and Affiliations

  • J. Krupčik
    • 1
  • E. Matisová
    • 1
  • J. Garaj
    • 1
  • L. Soják
    • 2
  • V. G. Brezkin
    • 3
  1. 1.Department of Analytical Chemistry, Faculty of Chemical TechnologySlovak Technical UniversityBratislavaCzechoslovakia
  2. 2.Chemical InstituteComenius UniversityBratislavaCzechoslovakia
  3. 3.Topchiev's Institute of Petroleum Chemical SynthesisAcademy of SciencesMoscowU.S.S.R.

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