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Twenty three years of dicarbollide extraction of metals research and applications

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The history of the development of solvent extraction investigations with dicarbollides for the separation of metals is briefly treated and some inaccuracies in previous reviews are commented on.

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    M. Benešová, The study of the conditions of the technology of the extraction separation of Am and Cm. I. Extraction of Eu and Ce by polyhedral carborane anion in the presence of the polyethylene glycols into nitrobenzene. Report ÚJV-3820 CH (1976).

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    M. Benešová, L. Kuča, H. Petržílová, Extraction of Am and Eu dicarbollides from acidic solutions. Report ÚJV-4087 CH (1977).

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    M. Kyrš, L. Kadlecová, J. Rais, P. Selucký, J. Teplý, Ya.B. Galkin, R.I. Ljubtsev, S.I. Sovnyi, V.N. Romanovskii, N.S. Tikhonov, G.N. Shishkin, Isolation of Cs and Sr with a polyhedral carborane complex from the raffinate of the first extraction cycles of reprocessing fuel elements, 4th Symp. COMECON on Reprocessing of Nuclear Fuel, March 28, 1977, Mariánské Lázné, Czechoslovakia, Vol. 1., p. 246.

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    V.A. Babain, V.P. Popik, A.Yu. Shchadrin, J. Rais, P. Selucký, M. Kyrš, Back-extraction of Cs, Sr and Ba in systems with chlorated cobalt dicarbollides, 3rd Intern. Conf. Sepn. Ionic Solutes, SIS '89, Dec. 4, 1989, Stará Lesná, Czechoslovakia.

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Kyrš, M. Twenty three years of dicarbollide extraction of metals research and applications. Journal of Radioanalytical and Nuclear Chemistry Letters 187, 185–195 (1994).

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  • Physical Chemistry
  • Inorganic Chemistry
  • Solvent Extraction
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