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Isotope exchange between bis/diethyl dithiocarbamate/ copper/II/ complex and Cu2+ ion

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Abstract

Isotope exchange behaviour of bis/diethyl dithiocarbamate/ copper/II/ complex has been studied at 30 °C and 40 °C varying the concentration of the complex and metal ion. Results indicate that the complex is labile in chloroform dimethyl sulphoxide medium. Increase in concentration has significant effect on the rate of the reaction. Similarly the increase in temperature increased the rate of the reaction.

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References

  1. 1.

    S. Bajo, A. Wyttenbach,Anal. Chem., 51 /1979/ 376.

  2. 2.

    B. Ya. Spivakov, Yu.A. Zolotov,J. Anal. Chem., USSR 24 /1969/ 1437.

  3. 3.

    G.D. Thorn, R.A. Ludwig, The Dithiocarbamates and Related Compounds, Elsevier, New York, 1962.

  4. 4.

    R.J. Magee,Revs. Anal. Chem., /1973/ 333.

  5. 5.

    D.W.P. Boyd, S. Mitra, L.C. Raston, L.G. Robottam, H.A. White,J. Chem. Soc. Dalton Trans., 1 /1981/ 13.

  6. 6.

    M. Kastanski, S. Magas,Bull. Acad. Pol. Sci. Ser. Sci. Chem., 28 /1980/ 423.

  7. 7.

    J. Sachinidis, W.M. Grant,Aust. J. Chem., 34 /1981/ 2195.

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Chetty, A.N., Ramadevi, P. & Naidu, G.R.K. Isotope exchange between bis/diethyl dithiocarbamate/ copper/II/ complex and Cu2+ ion. Journal of Radioanalytical and Nuclear Chemistry Letters 117, 347–352 (1987). https://doi.org/10.1007/BF02166038

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Keywords

  • Physical Chemistry
  • Inorganic Chemistry
  • Chloroform
  • Dimethyl
  • Isotope Exchange