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Journal of Radioanalytical and Nuclear Chemistry

, Volume 93, Issue 3, pp 133–140 | Cite as

Effect of metal oxides on the gamma radiolysis of ammonium nitrate

  • S. F. Patil
  • S. A. Bhoite
  • A. G. Bedekar
Article

Abstract

The studies of radiation decomposition of ammonium nitrate in the presence of MnO2, PbO and V2O5 with the absorbed dose reveal that MnO2 retards while PbO and V2O5 accelerate the rate of radiolysis. G/NO 2 / values were found to increase with the mole% of V2O5 in an admixture. The results are explained on the basis of electron donor-acceptor properties of oxides affecting the equilibrium concentration of electrons present in pure ammonium nitrate in the presence of the added oxides.

Keywords

Oxide Radiation Ammonium Nitrate Physical Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. R. Jones,J. Chem. Phys., 35/1961/751.Google Scholar
  2. 2.
    M. Khare, E. R. Johnson,J. Phys. Chem., 74 /1970/ 4085.Google Scholar
  3. 3.
    S. Kaucic, A. G. Maddock,Trans. Faraday Soc., 65/1960/1083.Google Scholar
  4. 4.
    K. G. Dharmawardena, A. G. Maddock,Chem. Commun., 9/1970/549.Google Scholar
  5. 5.
    J. Cunningham, H. G. Heal,Trans. Faraday, Soc., 54/1957/1355.Google Scholar
  6. 6.
    J. Cunningham,J. Am. Chem. Soc., 85/1963/1772.Google Scholar
  7. 7.
    M. B. Shinn,Ind. Eng. Chem., Analyt. Edn., 1333/1941/.Google Scholar
  8. 8.
    N. F. Kershaw, N. S. Camberlin,Ind. Eng. Chem., Analyt. Edn., 14/1942/312.Google Scholar
  9. 9.
    V. A. Nevostruev, Yu. A. Zakharov,Kinetika i Kataliz, 8/1967/210.Google Scholar
  10. 10.
    Yu. A. Zakharov, V. A. Nevostruev, Radiation Physics of Nonmetallic Crystals, Naukov Dumka, Kiev, 1967, 397.Google Scholar
  11. 11.
    Yu. A. Zakharov, S. M. Ryabykh, V. D., Mirakov,Izu. Tomsk Politekh Inst. 8/1970/251.Google Scholar

Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • S. F. Patil
    • 1
  • S. A. Bhoite
    • 1
  • A. G. Bedekar
    • 1
  1. 1.Department of ChemistryUniversity of PoonaPuneIndia

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